CHEMISTRY: MOLECULAR NATURE ALEKS ACCESS
9th Edition
ISBN: 9781265335236
Author: SILBERBERG
Publisher: MCG
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Question
Chapter 19, Problem 19.96P
Interpretation Introduction
Interpretation:
The balanced equation has to be written for the reaction of
Concept Introduction:
Balanced equation:
The total number of atoms or ions that are present in both sides (i.e. reactant and product side) of the equation is equal means given equation is balanced equation.
Expert Solution & Answer
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Students have asked these similar questions
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 19 Solutions
CHEMISTRY: MOLECULAR NATURE ALEKS ACCESS
Ch. 19.1 - Calculate the pH of a buffer consisting of 0.50 M...Ch. 19.1 - Prob. 19.1BFPCh. 19.1 - Prob. 19.2AFPCh. 19.1 - The molecular scenes below show three samples of a...Ch. 19.1 - Prob. 19.3AFPCh. 19.1 - What is the component concentration ratio, [NH3]/...Ch. 19.2 - A chemist titrates 20.00 mL of 0.2000 M HBrO (Ka =...Ch. 19.2 - For the titration of 30.00 mL of 0.1000 M benzoic...Ch. 19.3 - Write the ion-product expression at equilibrium...Ch. 19.3 - Prob. 19.5BFP
Ch. 19.3 - Prob. 19.6AFPCh. 19.3 - Prob. 19.6BFPCh. 19.3 - Prob. 19.7AFPCh. 19.3 - Prob. 19.7BFPCh. 19.3 - Prob. 19.8AFPCh. 19.3 - Prob. 19.8BFPCh. 19.3 - Prob. 19.9AFPCh. 19.3 - Prob. 19.9BFPCh. 19.3 - Prob. 19.10AFPCh. 19.3 - Prob. 19.10BFPCh. 19.3 - Prob. 19.11AFPCh. 19.3 - Prob. 19.11BFPCh. 19.3 - Prob. 19.12AFPCh. 19.3 - Prob. 19.12BFPCh. 19.4 - Cyanide ion is toxic because it forms stable...Ch. 19.4 - Prob. 19.13BFPCh. 19.4 - Prob. 19.14AFPCh. 19.4 - Calculate the solubility of PbCl2 in 0.75 M NaOH....Ch. 19 - Prob. 19.1PCh. 19 - Prob. 19.2PCh. 19 - Prob. 19.3PCh. 19 - Prob. 19.4PCh. 19 - Prob. 19.5PCh. 19 - Prob. 19.6PCh. 19 - Prob. 19.7PCh. 19 - Prob. 19.8PCh. 19 - Does the pH increase or decrease with each of the...Ch. 19 - The scenes below depict solutions of the same...Ch. 19 - The scenes below show three samples of a buffer...Ch. 19 - What are the [H3O+] and the pH of a propanoic...Ch. 19 - What are the [H3O+] and the pH of a benzoic...Ch. 19 - Prob. 19.14PCh. 19 - Prob. 19.15PCh. 19 - Prob. 19.16PCh. 19 - Find the pH of a buffer that consists of 0.95 M...Ch. 19 - Prob. 19.18PCh. 19 - Prob. 19.19PCh. 19 - Prob. 19.20PCh. 19 - Find the pH of a buffer that consists of 0.50 M...Ch. 19 - A buffer consists of 0.22 M KHCO3 and 0.37 M...Ch. 19 - A buffer consists of 0.50 M NaH2PO4 and 0.40 M...Ch. 19 - What is the component concentration ratio,...Ch. 19 - Prob. 19.25PCh. 19 - Prob. 19.26PCh. 19 - Prob. 19.27PCh. 19 - Prob. 19.28PCh. 19 - A buffer that contains 0.40 M of a base, B, and...Ch. 19 - A buffer that contains 0.110 M HY and 0.220 M Y−...Ch. 19 - A buffer that contains 1.05 M B and 0.750 M BH+...Ch. 19 - A buffer is prepared by mixing 204 mL of 0.452 M...Ch. 19 - A buffer is prepared by mixing 50.0 mL of 0.050 M...Ch. 19 - Prob. 19.34PCh. 19 - Prob. 19.35PCh. 19 - Prob. 19.36PCh. 19 - Choose specific acid-base conjugate pairs to make...Ch. 19 - An industrial chemist studying bleaching and...Ch. 19 - Oxoanions of phosphorus are buffer components in...Ch. 19 - The scenes below depict the relative...Ch. 19 - Prob. 19.41PCh. 19 - What species are in the buffer region of a weak...Ch. 19 - Prob. 19.43PCh. 19 - Prob. 19.44PCh. 19 - Prob. 19.45PCh. 19 - Prob. 19.46PCh. 19 - Prob. 19.47PCh. 19 - Prob. 19.48PCh. 19 - Prob. 19.49PCh. 19 - Prob. 19.50PCh. 19 - Prob. 19.51PCh. 19 - Prob. 19.52PCh. 19 - Prob. 19.53PCh. 19 - Prob. 19.54PCh. 19 - Prob. 19.55PCh. 19 - Prob. 19.56PCh. 19 - Prob. 19.57PCh. 19 - Prob. 19.58PCh. 19 - Prob. 19.59PCh. 19 - Prob. 19.60PCh. 19 - Prob. 19.61PCh. 19 - Use figure 19.9 to find an indicator for these...Ch. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - Prob. 19.65PCh. 19 - Prob. 19.66PCh. 19 - Write the ion-product expressions for (a) silver...Ch. 19 - Write the ion-product expressions for (a)...Ch. 19 - Write the ion-product expressions for (a) calcium...Ch. 19 - Prob. 19.70PCh. 19 - The solubility of silver carbonate is 0.032 M at...Ch. 19 - Prob. 19.72PCh. 19 - Prob. 19.73PCh. 19 - The solubility of calcium sulfate at 30°C is 0.209...Ch. 19 - Prob. 19.75PCh. 19 - Prob. 19.76PCh. 19 - Prob. 19.77PCh. 19 - Calculate the molar solubility of Ag2SO4 in (a)...Ch. 19 - Prob. 19.79PCh. 19 - Prob. 19.80PCh. 19 - Prob. 19.81PCh. 19 - Prob. 19.82PCh. 19 - Prob. 19.83PCh. 19 - Write equations to show whether the solubility of...Ch. 19 - Prob. 19.85PCh. 19 - Prob. 19.86PCh. 19 - Prob. 19.87PCh. 19 - Does any solid PbCl2 form when 3.5 mg of NaCl is...Ch. 19 - Prob. 19.89PCh. 19 - Prob. 19.90PCh. 19 - Prob. 19.91PCh. 19 - A 50.0-mL volume of 0.50 M Fe(NO3)3 is mixed with...Ch. 19 - Prob. 19.93PCh. 19 - Prob. 19.94PCh. 19 - Write a balanced equation for the reaction of in...Ch. 19 - Prob. 19.96PCh. 19 - Prob. 19.97PCh. 19 - Prob. 19.98PCh. 19 - What is [Ag+] when 25.0 mL each of 0.044 M AgNO3...Ch. 19 - Prob. 19.100PCh. 19 - Prob. 19.101PCh. 19 - Prob. 19.102PCh. 19 - When 0.84 g of ZnCl2 is dissolved in 245 mL of...Ch. 19 - When 2.4 g of Co(NO3)2 is dissolved in 0.350 L of...Ch. 19 - Prob. 19.105PCh. 19 - A microbiologist is preparing a medium on which to...Ch. 19 - As an FDA physiologist, you need 0.700 L of formic...Ch. 19 - Tris(hydroxymethyl)aminomethane [(HOCH2)3CNH2],...Ch. 19 - Water flowing through pipes of carbon steel must...Ch. 19 - Gout is caused by an error in metabolism that...Ch. 19 - In the process of cave formation (Section 19.3),...Ch. 19 - Phosphate systems form essential buffers in...Ch. 19 - The solubility of KCl is 3.7 M at 20°C. Two...Ch. 19 - It is possible to detect NH3 gas over 10−2 M NH3....Ch. 19 - Manganese(II) sulfide is one of the compounds...Ch. 19 - The normal pH of blood is 7.40 ± 0.05 and is...Ch. 19 - A bioengineer preparing cells for cloning bathes a...Ch. 19 - Sketch a qualitative curve for the titration of...Ch. 19 - Prob. 19.119PCh. 19 - The scene at right depicts a saturated solution of...Ch. 19 - Prob. 19.121PCh. 19 - The acid-base indicator ethyl orange turns from...Ch. 19 - Prob. 19.123PCh. 19 - Prob. 19.124PCh. 19 - Prob. 19.125PCh. 19 - Prob. 19.126PCh. 19 - Prob. 19.127PCh. 19 - Prob. 19.128PCh. 19 - Calcium ion present in water supplies is easily...Ch. 19 - Calculate the molar solubility of Hg2C2O4 (Ksp =...Ch. 19 - Environmental engineers use alkalinity as a...Ch. 19 - Human blood contains one buffer system based on...Ch. 19 - Quantitative analysis of Cl− ion is often...Ch. 19 - An ecobotanist separates the components of a...Ch. 19 - Some kidney stones form by the precipitation of...Ch. 19 - Prob. 19.136PCh. 19 - Prob. 19.137PCh. 19 - Because of the toxicity of mercury compounds,...Ch. 19 - A 35.0-mL solution of 0.075 M CaCl2 is mixed with...Ch. 19 - Rainwater is slightly acidic due to dissolved CO2....Ch. 19 - Prob. 19.141PCh. 19 - Ethylenediaminetetraacetic acid (abbreviated...Ch. 19 - Buffers that are based on...Ch. 19 - NaCl is purified by adding HCl to a saturated...Ch. 19 - Scenes A to D represent tiny portions of 0.10 M...Ch. 19 - Prob. 19.146PCh. 19 - Prob. 19.147PCh. 19 - Prob. 19.148P
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY