(a) Interpretation: The problems that are likely to be encountered in the given synthesis is to be stated. Concept introduction: Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

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Answer 1

Question

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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2. Use Hess's law to calculate the AH (in kJ) for: rxn CIF(g) + F2(g) → CIF 3 (1) using the following information: 2CIF(g) + O2(g) → Cl₂O(g) + OF 2(g) AH = 167.5 kJ ΔΗ 2F2 (g) + O2(g) → 2 OF 2(g) 2C1F3 (1) + 202(g) → Cl₂O(g) + 3 OF 2(g) о = = -43.5 kJ AH = 394.1kJ

ci Draw the major product(s) of the following reactions: (3 pts) CH3 HNO3/H2SO4 HNO3/ H2SO4 OCH3 (1 pts)

Provide the product for the reaction

Answer 2

Question

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 3

Question

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 4

Question

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

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Answer 5

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 6

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Answer 7

Chapter 19, Problem 19.63AP

Interpretation Introduction

(a)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

Grignard reagents are organometallic compounds which are prepared using alkyl halides in the presence of magnesium metal in dry ether. These reagents act as strong nucleophiles and bases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The problems that are likely to be encountered in the given synthesis is to be stated.

Concept introduction:

The reaction of an aldehyde or a ketone with ethylidene triphenylphosphine that is phosphorous Ylides results in the formation of alkene as the final product. This reaction is commonly known as Wittig reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

Solution Summary: The author explains that the selective attack of Grignard reagent to the ketonic carbon of the compound cannot take place. The reaction of an aldehyde or a ketone with ethyliden

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Chapter 19 Solutions