(a) Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified. Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

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Answer 1

Question

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

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What are the IUPAC Names of all the compounds in the picture?

1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

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Answer 3

Question

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

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Answer 4

Question

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

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Answer 5

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 6

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Answer 7

Chapter 19, Problem 19.4P

Interpretation Introduction

(a)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituent at appropriate carbon atoms.

Answer 10

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 13

Interpretation Introduction

(d)

Interpretation: The IUPAC name for the given metal salt of a carboxylate ion is to be identified.

Concept introduction:International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involvesthe identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19 - Prob. 19.1P Ch. 19 - Problem 19.2 Give the structure corresponding to...Ch. 19 - Problem 19.3 Draw the structure corresponding to...Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Problem 19.6 Rank the following compounds in order...Ch. 19 - Problem 19.7 Explain how you could use IR...Ch. 19 - Prob. 19.8P Ch. 19 - Problem 19.9 How many tetrahedral stereogenic...Ch. 19 - Problem 19.10 What alcohol can be oxidized to each...

Solution Summary: The author explains that the IUPAC name for the given metal salt of a carboxylate ion is lithium benzoate.

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