GENERAL,ORGANIC,+BIOCHEMISTRY
10th Edition
ISBN: 9781260148954
Author: Denniston
Publisher: RENT MCG
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Chapter 19, Problem 19.48QP
Interpretation Introduction
Interpretation:
The region of an enzyme that is responsible for its specificity has to be determined.
Concept Introduction:
The active site is the specific region located on the surface of the enzyme in the form of cleft or pocket into which the substrate attaches during a biochemical reaction. The interaction between the substrate and the enzyme is highly specific. The complimentary of the shape of the substrate and the active site allows for this specific interaction.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 19 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY
Ch. 19.8 - Prob. 19.12QCh. 19.10 - Prob. 19.13QCh. 19.10 - Prob. 19.14QCh. 19.10 - Prob. 19.15QCh. 19.10 - Prob. 19.16QCh. 19.11 - Prob. 19.17QCh. 19.11 - Prob. 19.18QCh. 19.11 - Prob. 19.19QCh. 19.11 - Prob. 19.20QCh. 19 - Prob. 19.21QP
Ch. 19 - Prob. 19.22QPCh. 19 - Prob. 19.23QPCh. 19 - Prob. 19.24QPCh. 19 - Prob. 19.25QPCh. 19 - Prob. 19.26QPCh. 19 - Define the term substrate.
Ch. 19 - Prob. 19.28QPCh. 19 - Prob. 19.29QPCh. 19 - Prob. 19.30QPCh. 19 - Prob. 19.31QPCh. 19 - Prob. 19.32QPCh. 19 - Prob. 19.33QPCh. 19 - Prob. 19.34QPCh. 19 - Prob. 19.35QPCh. 19 - Prob. 19.36QPCh. 19 - Prob. 19.37QPCh. 19 - Prob. 19.38QPCh. 19 - Prob. 19.39QPCh. 19 - Prob. 19.40QPCh. 19 - Prob. 19.41QPCh. 19 - Prob. 19.42QPCh. 19 - Prob. 19.43QPCh. 19 - Prob. 19.44QPCh. 19 - Prob. 19.45QPCh. 19 - Prob. 19.46QPCh. 19 - Prob. 19.47QPCh. 19 - Prob. 19.48QPCh. 19 - Prob. 19.49QPCh. 19 - Prob. 19.50QPCh. 19 - Prob. 19.51QPCh. 19 - Prob. 19.52QPCh. 19 - Prob. 19.53QPCh. 19 - Prob. 19.54QPCh. 19 - Prob. 19.55QPCh. 19 - Prob. 19.56QPCh. 19 - Prob. 19.57QPCh. 19 - Prob. 19.58QPCh. 19 - Prob. 19.59QPCh. 19 - Prob. 19.60QPCh. 19 - Prob. 19.61QPCh. 19 - Prob. 19.62QPCh. 19 - Prob. 19.63QPCh. 19 - Prob. 19.64QPCh. 19 - Prob. 19.65QPCh. 19 - Prob. 19.66QPCh. 19 - Prob. 19.67QPCh. 19 - Prob. 19.68QPCh. 19 - Prob. 19.69QPCh. 19 - Prob. 19.70QPCh. 19 - Prob. 19.71QPCh. 19 - Prob. 19.72QPCh. 19 - Prob. 19.73QPCh. 19 - Prob. 19.74QPCh. 19 - Prob. 19.75QPCh. 19 - Prob. 19.76QPCh. 19 - Prob. 19.77QPCh. 19 - Prob. 19.78QPCh. 19 - Prob. 19.79QPCh. 19 - Three proenzymes that are involved in digestion of...Ch. 19 - Prob. 19.81QPCh. 19 - What is the benefit for an enzyme such as...Ch. 19 - Prob. 19.83QPCh. 19 - Prob. 19.84QPCh. 19 - Prob. 19.85QPCh. 19 - Prob. 19.86QPCh. 19 - Prob. 19.87QPCh. 19 - Prob. 19.88QPCh. 19 - Prob. 19.89QPCh. 19 - Prob. 19.90QPCh. 19 - Prob. 19.91QPCh. 19 - Prob. 19.92QPCh. 19 - Prob. 19.93QPCh. 19 - What properties are shared by chymotrypsin,...Ch. 19 - Prob. 19.95QPCh. 19 - Prob. 19.96QPCh. 19 - Prob. 19.97QPCh. 19 - Prob. 19.98QPCh. 19 - Prob. 19.99QPCh. 19 - Prob. 19.100QPCh. 19 - List the enzymes whose levels are elevated in...Ch. 19 - Prob. 19.102QPCh. 19 - Prob. 19.103QPCh. 19 - Prob. 19.104QPCh. 19 - Prob. 1MCPCh. 19 - Consider the Chapter Map, and explain the...Ch. 19 - Prob. 3MCPCh. 19 - Prob. 4MCPCh. 19 - Prob. 5MCPCh. 19 - Prob. 6MCPCh. 19 - Prob. 7MCPCh. 19 - Prob. 8MCPCh. 19 - Prob. 9MCP
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