
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 9781319416942
Author: Harris
Publisher: VST
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Chapter 19, Problem 19.3P
Interpretation Introduction
Interpretation:
Advantages and disadvantages of reduction in monochromator slit width have to be stated.
Concept Introduction:
Various components of spectrophotometer include light source that is usually tungsten or a deuterium lamp enables absorption of light by sample. Then a monochromator that essentially selects one particular wavelength and allows it to pass across sample cuvette, beam chopper splits incident light beam path amongst reference cell and sample cell; analyte within sample absorbs light. And a reference solution has same solvent that is found in analyte sample cuvette, the detector transforms photons into specific electrical response that is further enhanced by amplifier and data is displayed.
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Synthesis of Dibenzalacetone
[References]
Draw structures for the carbonyl electrophile and enolate nucleophile that react to give the enone below.
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H
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7/8 items
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You do not have to consider stereochemistry.
. Draw the enolate ion in its carbanion form.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
⚫ Separate multiple reactants using the + sign from the drop-down menu.
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4
Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)
Chapter 19 Solutions
EBK EXPLORING CHEMICAL ANALYSIS
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