Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given. Concept Introduction: Nomenclature of coordination compounds: Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are, In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named. If one type of ligand is comes more times means it can be named with prefix: ( 1 ) mono- (usually omitted), ( 2 ) di-, ( 3 ) tri-, ( 4 ) tetra flowed by its name. Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

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Answer 1

Question

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained. Draw the structures of these fragments.

For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.

Answer 2

Question

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

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Answer 3

Question

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

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Answer 4

Question

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

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Answer 5

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 6

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

Answer 7

Chapter 19, Problem 19.32QE

(a)

Interpretation Introduction

Interpretation:

Formula of hexaaquachromium(III) hexacyanoferrate(III) complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 9

(b)

Interpretation Introduction

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 10

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 11

(c)

Interpretation Introduction

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 12

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 13

(d)

Interpretation Introduction

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 14

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 15

(e)

Interpretation Introduction

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 16

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Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. 19 - Prob. 19.1QE Ch. 19 - Prob. 19.2QE Ch. 19 - Prob. 19.3QE Ch. 19 - Prob. 19.4QE Ch. 19 - Prob. 19.5QE Ch. 19 - Prob. 19.6QE Ch. 19 - Prob. 19.7QE Ch. 19 - Prob. 19.8QE Ch. 19 - Prob. 19.9QE Ch. 19 - Prob. 19.10QE

Solution Summary: The author explains the IUPAC system of nomenclature of coordination compounds.

Concept explainers

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)

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Chapter 19 Solutions

Solution Summary: The author explains the IUPAC system of nomenclature of coordination compounds.

Concept explainers

Interpretation: Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given. Concept Introduction: Refer to part (a)

Interpretation: Formula of carbonylpentacyanocobaltate(III) complex has to be given. Concept Introduction: Refer to part (a)

Interpretation: Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given. Concept Introduction: Refer to part (a)

Interpretation: Formula of pentaaquathiocyanatoiron(III) complex has to be given. Concept Introduction: Refer to part (a)

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Chapter 19 Solutions

Interpretation:

Formula of bromochlorobis(ethylenediamine)cobalt(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of carbonylpentacyanocobaltate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of (diethylenetriamine)trinitrochromium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of pentaaquathiocyanatoiron(III) complex has to be given.

Concept Introduction:

Refer to part (a)