EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
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Chapter 19, Problem 19.2P
Interpretation Introduction

Interpretation:

Whether tungsten or a deuterium lamp has to be used to get 300 nm radiation has to be identified.

Concept Introduction:

In electromagnetic radiation, the key radiations are gamma rays, ultraviolet and UV visible light and infrared radiation. The range of wavelength for theses radiations are as follows:

RadiationWavelength-range(m)Gamma rays1012-1010X-rays1010-108Ultraviolet108-4×107Visible light4×107-7×107Infrared106-102Microwaves102-1Radiowaves1-104

One of the key components of double-beam instruments is light source of visible and ultraviolet radiation. Tungsten lamp that has filament at around 3000 K is preferred in ultraviolet spectroscopy while deuterium lamp is more appropriate for visible and region near infrared radiation.

Besides these two lamps, other sources include electric discharge that comprise of gases such as mercury vapor or xenon.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
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