
(a)
Interpretation:
The overall orders for the given reactions of rate law have to be calculated.
Concept introduction:
Order of a reaction: The sum of exponents of the concentrations in the rate law for the reaction is said to be order of a reaction.
- The simple technique to calculate the order of a given rate law is by summing the values present in squares values of reactant concentrations we can get the overall order for the given reactions.
Rate law: It is an equation that related to the
(b)
Interpretation:
The overall orders for the given reactions of rate law have to be calculated.
Concept introduction:
Order of a reaction: The sum of exponents of the concentrations in the rate law for the reaction is said to be order of a reaction.
- The simple technique to calculate the order of a given rate law is by summing the values present in squares values of reactant concentrations we can get the overall order for the given reactions.
Rate law: It is an equation that related to the rate of reaction to the concentrations or pressures of substrates (reactants). It is also said to be as rate equation.
(c)
Interpretation:
The overall orders for the given reactions of rate law have to be calculated.
Concept introduction:
Order of a reaction: The sum of exponents of the concentrations in the rate law for the reaction is said to be order of a reaction.
- The simple technique to calculate the order of a given rate law is by summing the values present in squares values of reactant concentrations we can get the overall order for the given reactions.
Rate law: It is an equation that related to the rate of reaction to the concentrations or pressures of substrates (reactants). It is also said to be as rate equation.
(d)
Interpretation:
The overall orders for the given reactions of rate law have to be calculated.
Concept introduction:
Order of a reaction: The sum of exponents of the concentrations in the rate law for the reaction is said to be order of a reaction.
- The simple technique to calculate the order of a given rate law is by summing the values present in squares values of reactant concentrations we can get the overall order for the given reactions.
Rate law: It is an equation that related to the rate of reaction to the concentrations or pressures of substrates (reactants). It is also said to be as rate equation.

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Chapter 19 Solutions
EBK CHEMISTRY: ATOMS FIRST
- Provide the reasonable steps to achieve the following synthesis.arrow_forwardWhen anisole is treated with excess bromine, the reaction gives a product which shows two singlets in 1H NMR. Draw the product.arrow_forward(ii) Draw a reasonable mechanism for the following reaction: CI NaOH heat OH (hint: SNAr Reaction) :arrow_forward
- For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardConsider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forward
- For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forwardGiven the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
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