1 Keys To Studying Chemistry: Definitions, Units, And Problem Solving 2 The Components Of Matter 3 Stoichiometry Of Formulas And Equations 4 Three Major Classes Of Chemical Reactions 5 Gases And The Kinetic-molecular Theory 6 Thermochemistry: Energy Flow And Chemical Change 7 Quantum Theory And Atomic Structure 8 Electron Configuration And Chemical Periodicity 9 Models Of Chemical Bonding 10 The Shapes Of Molecules 11 Theories Of Covalent Bonding 12 Intermolecular Forces: Liquids, Solids, And Phase Changes 13 The Properties Of Mixtures: Solutions And Colloids 14 Periodic Patterns In The Main-group Elements 15 Organic Compounds And The Atomic Properties Of Carbon 16 Kinetics: Rates And Mechanisms Of Chemical Reactions 17 Equilibrium: The Extent Of Chemical Reactions 18 Acid-base Equilibria 19 Ionic Equilibria In Aqueous Systems 20 Thermodynamics: Entropy, Free Energy, And Reaction Direction 21 Electrochemistry: Chemical Change And Electrical Work 22 The Elements In Nature And Industry 23 Transition Elements And Their Coordination Compounds 24 Nuclear Reactions And Their Applications expand_more
19.1 Equilibria Of Acid-base Buffers 19.2 Acid-base Titration Curves 19.3 Equilibria Of Slightly Soluble Ionic Compounds 19.4 Equilibria Involving Complex Ions Chapter Questions expand_more
Problem 19.1P Problem 19.2P Problem 19.3P Problem 19.4P Problem 19.5P Problem 19.6P Problem 19.7P Problem 19.8P Problem 19.9P: Does the pH increase or decrease with each of the following additions, and does it do so to a large... Problem 19.10P: The scenes below depict solutions of the same HA/A− buffer (HA is red and blue and A− is red; other... Problem 19.11P: The scenes below show three samples of a buffer consisting of HA and A− (HA is green and blue and A−... Problem 19.12P: What are the [H3O+] and the pH of a propanoic acid–propanoate buffer that consists of 0.35 M... Problem 19.13P: What are the [H3O+] and the pH of a benzoic acid–benzoate buffer that consists of 0.33 M C6H5COOH... Problem 19.14P Problem 19.15P Problem 19.16P Problem 19.17P: Find the pH of a buffer that consists of 0.95 M HBrO and 0.68 M KBrO (pKa of HBrO = 8.64).
Problem 19.18P Problem 19.19P Problem 19.20P Problem 19.21P: Find the pH of a buffer that consists of 0.50 M methylamine (CH3NH2) and 0.60 M CH3NH3Cl (pKb of... Problem 19.22P: A buffer consists of 0.22 M KHCO3 and 0.37 M K2CO3. Carbonic acid is a diprotic acid with Ka1 = 4.5... Problem 19.23P: A buffer consists of 0.50 M NaH2PO4 and 0.40 M Na2HPO4. Phosphoric acid is a triprotic acid (Ka1 =... Problem 19.24P: What is the component concentration ratio, [Pr−]/[HPr], of a buffer that has a pH of 5.44 (Ka of HPr... Problem 19.25P Problem 19.26P Problem 19.27P Problem 19.28P Problem 19.29P: A buffer that contains 0.40 M of a base, B, and 0.25 M of its conjugate acid, BH+, has a pH of 8.88.... Problem 19.30P: A buffer that contains 0.110 M HY and 0.220 M Y− has a pH of 8.77. What is the pH after 0.0015 mol... Problem 19.31P: A buffer that contains 1.05 M B and 0.750 M BH+ has a pH of 9.50. What is the pH after 0.0050 mol of... Problem 19.32P: A buffer is prepared by mixing 204 mL of 0.452 M HCl and 0.500 L of 0.400 M sodium acetate. (See... Problem 19.33P: A buffer is prepared by mixing 50.0 mL of 0.050 M sodium bicarbonate and 10.7 mL of 0.10 M NaOH.... Problem 19.34P Problem 19.35P Problem 19.36P Problem 19.37P: Choose specific acid-base conjugate pairs to make the following buffers: (a) [OH−] ≈ 1×10−6 M; (b)... Problem 19.38P: An industrial chemist studying bleaching and sterilizing prepares several hypochlorite buffers. Find... Problem 19.39P: Oxoanions of phosphorus are buffer components in blood. For a KH2PO4/Na2HPO4 buffer with pH = 7.40... Problem 19.40P: The scenes below depict the relative concentrations of H3PO4, , and during a titration with aqueous... Problem 19.41P Problem 19.42P: What species are in the buffer region of a weak acid–strong base titration? How are they different... Problem 19.43P Problem 19.44P Problem 19.45P Problem 19.46P Problem 19.47P Problem 19.48P Problem 19.49P Problem 19.50P Problem 19.51P Problem 19.52P Problem 19.53P Problem 19.54P Problem 19.55P Problem 19.56P Problem 19.57P Problem 19.58P Problem 19.59P Problem 19.60P Problem 19.61P Problem 19.62P: Use figure 19.9 to find an indicator for these titrations:
0.25 M C6H5COOH (see Appendix C) with... Problem 19.63P Problem 19.64P Problem 19.65P Problem 19.66P Problem 19.67P: Write the ion-product expressions for (a) silver carbonate; (b) barium fluoride; (c) copper(II)... Problem 19.68P: Write the ion-product expressions for (a) iron(III) hydroxide; (b) barium phosphate; (c) magnesium... Problem 19.69P: Write the ion-product expressions for (a) calcium chromate; (b) silver cyanide; (c) silver... Problem 19.70P Problem 19.71P: The solubility of silver carbonate is 0.032 M at 20°C. Calculate its Ksp.
Problem 19.72P Problem 19.73P Problem 19.74P: The solubility of calcium sulfate at 30°C is 0.209 g/100. mL solution. Calculate its Ksp.
Problem 19.75P Problem 19.76P Problem 19.77P Problem 19.78P: Calculate the molar solubility of Ag2SO4 in (a) 0.22 M AgNO3 and (b) 0.22 M Na2SO4. (See Appendix... Problem 19.79P Problem 19.80P Problem 19.81P Problem 19.82P Problem 19.83P Problem 19.84P: Write equations to show whether the solubility of either of the following is affected by pH: (a)... Problem 19.85P Problem 19.86P Problem 19.87P Problem 19.88P: Does any solid PbCl2 form when 3.5 mg of NaCl is dissolved in 0.250 L of 0.12 M Pb(NO3)2?
Problem 19.89P Problem 19.90P Problem 19.91P Problem 19.92P: A 50.0-mL volume of 0.50 M Fe(NO3)3 is mixed with 125 mL of 0.25 M Cd(NO3)2.
If aqueous NaOH is... Problem 19.93P Problem 19.94P Problem 19.95P: Write a balanced equation for the reaction of in aqueous KCN.
Problem 19.96P Problem 19.97P Problem 19.98P Problem 19.99P: What is [Ag+] when 25.0 mL each of 0.044 M AgNO3 and 0.57 M Na2S2O3 are mixed? [Kf of Ag ]?
Problem 19.100P Problem 19.101P Problem 19.102P Problem 19.103P: When 0.84 g of ZnCl2 is dissolved in 245 mL of 0.150 M NaCN, what are [Zn2+], , and [CN−] [Kf of =... Problem 19.104P: When 2.4 g of Co(NO3)2 is dissolved in 0.350 L of 0.22 M KOH, what are [Co2+], [], and [OH−] [Kf of ... Problem 19.105P Problem 19.106P: A microbiologist is preparing a medium on which to culture E. coli bacteria. She buffers the medium... Problem 19.107P: As an FDA physiologist, you need 0.700 L of formic acid–formate buffer with a pH of 3.74. (a) What... Problem 19.108P: Tris(hydroxymethyl)aminomethane [(HOCH2)3CNH2], known as TRIS, is a weak base used in biochemical... Problem 19.109P: Water flowing through pipes of carbon steel must be kept at pH 5 or greater to limit corrosion. If... Problem 19.110P: Gout is caused by an error in metabolism that leads to a buildup of uric acid in body fluids, which... Problem 19.111P: In the process of cave formation (Section 19.3), the dissolution of CO2 (equation 1) has a Keq of... Problem 19.112P: Phosphate systems form essential buffers in organisms. Calculate the pH of a buffer made by... Problem 19.113P: The solubility of KCl is 3.7 M at 20°C. Two beakers each contain 100. mL of saturated KCl solution:... Problem 19.114P: It is possible to detect NH3 gas over 10−2 M NH3. To what pH must 0.15 M NH4Cl be raised to form... Problem 19.115P: Manganese(II) sulfide is one of the compounds found in the nodules on the ocean floor that may... Problem 19.116P: The normal pH of blood is 7.40 ± 0.05 and is controlled in part by the buffer system.
Assuming that... Problem 19.117P: A bioengineer preparing cells for cloning bathes a small piece of rat epithelial tissue in a TRIS... Problem 19.118P: Sketch a qualitative curve for the titration of ethylenediamine, H2NCH2CH2NH2, with 0.1 M HCl.
Problem 19.119P Problem 19.120P: The scene at right depicts a saturated solution of MCl2(s) in the presence of dilute aqueous NaCl;... Problem 19.121P Problem 19.122P: The acid-base indicator ethyl orange turns from red to yellow over the pH range 3.4 to 4.8. Estimate... Problem 19.123P Problem 19.124P Problem 19.125P Problem 19.126P Problem 19.127P Problem 19.128P Problem 19.129P: Calcium ion present in water supplies is easily precipitated as calcite (CaCO3):
Because the Ksp... Problem 19.130P: Calculate the molar solubility of Hg2C2O4 (Ksp = 1.75×10−13) in 0.13 M Hg2(NO3)2.
Problem 19.131P: Environmental engineers use alkalinity as a measure of the capacity of carbonate buffering systems... Problem 19.132P: Human blood contains one buffer system based on phosphate species and one based on carbonate... Problem 19.133P: Quantitative analysis of Cl− ion is often performed by a titration with silver nitrate, using sodium... Problem 19.134P: An ecobotanist separates the components of a tropical bark extract by chromatography. She discovers... Problem 19.135P: Some kidney stones form by the precipitation of calcium oxalate monohydrate (CaC2O4·H4O, Ksp = 2.3 ×... Problem 19.136P Problem 19.137P Problem 19.138P: Because of the toxicity of mercury compounds, mercury (I) chloride is used in antibacterial salves.... Problem 19.139P: A 35.0-mL solution of 0.075 M CaCl2 is mixed with 25.0 mL of 0.090 M BaCl2.
If aqueous KF is added,... Problem 19.140P: Rainwater is slightly acidic due to dissolved CO2. Use the following data to calculate the pH of... Problem 19.141P Problem 19.142P: Ethylenediaminetetraacetic acid (abbreviated H4EDTA) is a tetraprotic acid. Its salts are used to... Problem 19.143P: Buffers that are based on 3-morpholinopropanesulfonic acid (MOPS) are often used in RNA analysis.... Problem 19.144P: NaCl is purified by adding HCl to a saturated solution of NaCl (317 g/L). Will pure NaCl precipitate... Problem 19.145P: Scenes A to D represent tiny portions of 0.10 M aqueous solutions of a weak acid HA (red and blue;... Problem 19.146P Problem 19.147P Problem 19.148P format_list_bulleted