CHEMISTRY MOLECULAR NATURE OF MATTER
9th Edition
ISBN: 9781266177835
Author: SILBERBERG
Publisher: MCG
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Question
Chapter 19, Problem 19.118P
Interpretation Introduction
Interpretation:
A qualitative curve for the titration of ethylene diamine,
Concept Introduction:
Titration:
A titration is a technique where a solution of known concentration is used to determine the concentration of an unknown solution. Typically, the titrant (the know solution) is added from a burette to a known quantity of the analyte (the unknown solution) until the reaction is complete. Knowing the volume of titrant added allows the determination of the concentration of the unknown. Often, an indicator is used to usually signal the end of the reaction, the endpoint.
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B 1 of 2
Additional problems in preparation to Midterm #1:
1.) How can the following compounds be prepared using Diels-Alder reaction:
CH3 O
CN
(a)
(b)
CN
CH3
2.) What is the missing reagent in the shown reaction?
H3C
+ ?
H3C
H3C
CN
H3C
''CN
(၁)
H
3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene.
Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen.
4.) In the shown reaction, which will be the kinetic product and which will be the
thermodynamic product?
H3C
CI
H3C
HCI
H3C
+
5.) Which of the following molecules is aromatic?
(a)
(b)
(c)
H
6.) Which of the following molecules is aromatic?
(a)
(b)
(c)
7.) Write the mechanism for the shown reaction.
+
Ха
AICI 3
CI
8.) Suggest reagents that would convert benzene into the shown compounds.
CI
NO2
-8-6-6-8-a
(a)
(b)
(c)
(d)
(e)
(a)
SO3H
Br
Chapter 19 Solutions
CHEMISTRY MOLECULAR NATURE OF MATTER
Ch. 19.1 - Calculate the pH of a buffer consisting of 0.50 M...Ch. 19.1 - Prob. 19.1BFPCh. 19.1 - Prob. 19.2AFPCh. 19.1 - The molecular scenes below show three samples of a...Ch. 19.1 - Prob. 19.3AFPCh. 19.1 - What is the component concentration ratio, [NH3]/...Ch. 19.2 - A chemist titrates 20.00 mL of 0.2000 M HBrO (Ka =...Ch. 19.2 - For the titration of 30.00 mL of 0.1000 M benzoic...Ch. 19.3 - Write the ion-product expression at equilibrium...Ch. 19.3 - Prob. 19.5BFP
Ch. 19.3 - Prob. 19.6AFPCh. 19.3 - Prob. 19.6BFPCh. 19.3 - Prob. 19.7AFPCh. 19.3 - Prob. 19.7BFPCh. 19.3 - Prob. 19.8AFPCh. 19.3 - Prob. 19.8BFPCh. 19.3 - Prob. 19.9AFPCh. 19.3 - Prob. 19.9BFPCh. 19.3 - Prob. 19.10AFPCh. 19.3 - Prob. 19.10BFPCh. 19.3 - Prob. 19.11AFPCh. 19.3 - Prob. 19.11BFPCh. 19.3 - Prob. 19.12AFPCh. 19.3 - Prob. 19.12BFPCh. 19.4 - Cyanide ion is toxic because it forms stable...Ch. 19.4 - Prob. 19.13BFPCh. 19.4 - Prob. 19.14AFPCh. 19.4 - Calculate the solubility of PbCl2 in 0.75 M NaOH....Ch. 19 - Prob. 19.1PCh. 19 - Prob. 19.2PCh. 19 - Prob. 19.3PCh. 19 - Prob. 19.4PCh. 19 - Prob. 19.5PCh. 19 - Prob. 19.6PCh. 19 - Prob. 19.7PCh. 19 - Prob. 19.8PCh. 19 - Does the pH increase or decrease with each of the...Ch. 19 - The scenes below depict solutions of the same...Ch. 19 - The scenes below show three samples of a buffer...Ch. 19 - What are the [H3O+] and the pH of a propanoic...Ch. 19 - What are the [H3O+] and the pH of a benzoic...Ch. 19 - Prob. 19.14PCh. 19 - Prob. 19.15PCh. 19 - Prob. 19.16PCh. 19 - Find the pH of a buffer that consists of 0.95 M...Ch. 19 - Prob. 19.18PCh. 19 - Prob. 19.19PCh. 19 - Prob. 19.20PCh. 19 - Find the pH of a buffer that consists of 0.50 M...Ch. 19 - A buffer consists of 0.22 M KHCO3 and 0.37 M...Ch. 19 - A buffer consists of 0.50 M NaH2PO4 and 0.40 M...Ch. 19 - What is the component concentration ratio,...Ch. 19 - Prob. 19.25PCh. 19 - Prob. 19.26PCh. 19 - Prob. 19.27PCh. 19 - Prob. 19.28PCh. 19 - A buffer that contains 0.40 M of a base, B, and...Ch. 19 - A buffer that contains 0.110 M HY and 0.220 M Y−...Ch. 19 - A buffer that contains 1.05 M B and 0.750 M BH+...Ch. 19 - A buffer is prepared by mixing 204 mL of 0.452 M...Ch. 19 - A buffer is prepared by mixing 50.0 mL of 0.050 M...Ch. 19 - Prob. 19.34PCh. 19 - Prob. 19.35PCh. 19 - Prob. 19.36PCh. 19 - Choose specific acid-base conjugate pairs to make...Ch. 19 - An industrial chemist studying bleaching and...Ch. 19 - Oxoanions of phosphorus are buffer components in...Ch. 19 - The scenes below depict the relative...Ch. 19 - Prob. 19.41PCh. 19 - What species are in the buffer region of a weak...Ch. 19 - Prob. 19.43PCh. 19 - Prob. 19.44PCh. 19 - Prob. 19.45PCh. 19 - Prob. 19.46PCh. 19 - Prob. 19.47PCh. 19 - Prob. 19.48PCh. 19 - Prob. 19.49PCh. 19 - Prob. 19.50PCh. 19 - Prob. 19.51PCh. 19 - Prob. 19.52PCh. 19 - Prob. 19.53PCh. 19 - Prob. 19.54PCh. 19 - Prob. 19.55PCh. 19 - Prob. 19.56PCh. 19 - Prob. 19.57PCh. 19 - Prob. 19.58PCh. 19 - Prob. 19.59PCh. 19 - Prob. 19.60PCh. 19 - Prob. 19.61PCh. 19 - Use figure 19.9 to find an indicator for these...Ch. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - Prob. 19.65PCh. 19 - Prob. 19.66PCh. 19 - Write the ion-product expressions for (a) silver...Ch. 19 - Write the ion-product expressions for (a)...Ch. 19 - Write the ion-product expressions for (a) calcium...Ch. 19 - Prob. 19.70PCh. 19 - The solubility of silver carbonate is 0.032 M at...Ch. 19 - Prob. 19.72PCh. 19 - Prob. 19.73PCh. 19 - The solubility of calcium sulfate at 30°C is 0.209...Ch. 19 - Prob. 19.75PCh. 19 - Prob. 19.76PCh. 19 - Prob. 19.77PCh. 19 - Calculate the molar solubility of Ag2SO4 in (a)...Ch. 19 - Prob. 19.79PCh. 19 - Prob. 19.80PCh. 19 - Prob. 19.81PCh. 19 - Prob. 19.82PCh. 19 - Prob. 19.83PCh. 19 - Write equations to show whether the solubility of...Ch. 19 - Prob. 19.85PCh. 19 - Prob. 19.86PCh. 19 - Prob. 19.87PCh. 19 - Does any solid PbCl2 form when 3.5 mg of NaCl is...Ch. 19 - Prob. 19.89PCh. 19 - Prob. 19.90PCh. 19 - Prob. 19.91PCh. 19 - A 50.0-mL volume of 0.50 M Fe(NO3)3 is mixed with...Ch. 19 - Prob. 19.93PCh. 19 - Prob. 19.94PCh. 19 - Write a balanced equation for the reaction of in...Ch. 19 - Prob. 19.96PCh. 19 - Prob. 19.97PCh. 19 - Prob. 19.98PCh. 19 - What is [Ag+] when 25.0 mL each of 0.044 M AgNO3...Ch. 19 - Prob. 19.100PCh. 19 - Prob. 19.101PCh. 19 - Prob. 19.102PCh. 19 - When 0.84 g of ZnCl2 is dissolved in 245 mL of...Ch. 19 - When 2.4 g of Co(NO3)2 is dissolved in 0.350 L of...Ch. 19 - Prob. 19.105PCh. 19 - A microbiologist is preparing a medium on which to...Ch. 19 - As an FDA physiologist, you need 0.700 L of formic...Ch. 19 - Tris(hydroxymethyl)aminomethane [(HOCH2)3CNH2],...Ch. 19 - Water flowing through pipes of carbon steel must...Ch. 19 - Gout is caused by an error in metabolism that...Ch. 19 - In the process of cave formation (Section 19.3),...Ch. 19 - Phosphate systems form essential buffers in...Ch. 19 - The solubility of KCl is 3.7 M at 20°C. Two...Ch. 19 - It is possible to detect NH3 gas over 10−2 M NH3....Ch. 19 - Manganese(II) sulfide is one of the compounds...Ch. 19 - The normal pH of blood is 7.40 ± 0.05 and is...Ch. 19 - A bioengineer preparing cells for cloning bathes a...Ch. 19 - Sketch a qualitative curve for the titration of...Ch. 19 - Prob. 19.119PCh. 19 - The scene at right depicts a saturated solution of...Ch. 19 - Prob. 19.121PCh. 19 - The acid-base indicator ethyl orange turns from...Ch. 19 - Prob. 19.123PCh. 19 - Prob. 19.124PCh. 19 - Prob. 19.125PCh. 19 - Prob. 19.126PCh. 19 - Prob. 19.127PCh. 19 - Prob. 19.128PCh. 19 - Calcium ion present in water supplies is easily...Ch. 19 - Calculate the molar solubility of Hg2C2O4 (Ksp =...Ch. 19 - Environmental engineers use alkalinity as a...Ch. 19 - Human blood contains one buffer system based on...Ch. 19 - Quantitative analysis of Cl− ion is often...Ch. 19 - An ecobotanist separates the components of a...Ch. 19 - Some kidney stones form by the precipitation of...Ch. 19 - Prob. 19.136PCh. 19 - Prob. 19.137PCh. 19 - Because of the toxicity of mercury compounds,...Ch. 19 - A 35.0-mL solution of 0.075 M CaCl2 is mixed with...Ch. 19 - Rainwater is slightly acidic due to dissolved CO2....Ch. 19 - Prob. 19.141PCh. 19 - Ethylenediaminetetraacetic acid (abbreviated...Ch. 19 - Buffers that are based on...Ch. 19 - NaCl is purified by adding HCl to a saturated...Ch. 19 - Scenes A to D represent tiny portions of 0.10 M...Ch. 19 - Prob. 19.146PCh. 19 - Prob. 19.147PCh. 19 - Prob. 19.148P
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