a) Ethyl 1-ethylpropyl ether Interpretation: The structure of ethyl 1-ethylpropyl ether is to be drawn. Concept introduction: Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent. To draw: The structure of ethyl 1-ethylpropyl ether.

Question

Q3: Write in the starting alkyl bromide used to form the following products. Include any reactants, reagents, and solvents over the reaction arrow. If more than one step is required, denote separate steps by using 1), 2), 3), etc. H OH racemic OH OH 5 racemic

Answer 1

Question

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

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Q3: Write in the starting alkyl bromide used to form the following products. Include any reactants, reagents, and solvents over the reaction arrow. If more than one step is required, denote separate steps by using 1), 2), 3), etc. H OH racemic OH OH 5 racemic

Draw the Lewis structure of the SO3-O(CH3)2 complex shown in the bottom right of slide 2in lecture 3-3 (“Me” means a CH3 group) – include all valence electron pairs and formal charges.From this structure, should the complex be a stable molecule? Explain.

Predict all organic product(s), including stereoisomers when applicable.

Answer 2

Question

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

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Answer 3

Question

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

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Answer 4

Question

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

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Answer 5

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

Answer 6

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Answer 7

Chapter 18.SE, Problem 38AP

Interpretation Introduction

a) Ethyl 1-ethylpropyl ether

Interpretation:

The structure of ethyl 1-ethylpropyl ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To draw:

The structure of ethyl 1-ethylpropyl ether.

Answer 8

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Answer 9

Interpretation Introduction

b) Di (p-chlorophenyl) ether

Interpretation:

The structure of di (p-chlorophenyl) ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of di(p-chlorophenyl) ether.

Answer 10

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Answer 11

Interpretation Introduction

c) 3, 4-Dimethoxybenzoic acid

Interpretation:

The structure of 3, 4-dimethoxybenzoic acid ether is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 3, 4-dimethoxybenzoic acid.

Answer 12

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Answer 13

Interpretation Introduction

d) Cyclopentyloxycyclohexane

Interpretation:

The structure of cyclopentyloxycyclohexane is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of cyclopentyloxycyclohexane.

Answer 14

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

Answer 15

Interpretation Introduction

e) 4-Allyl-2-methoxyphenol (eugenol)

Interpretation:

The structure of 4-allyl-2-methoxyphenol (eugenol) is to be drawn.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The structure of 4-allyl-2-methoxyphenol (eugenol).

Answer 16

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Ch. 18.1 - Name the following ethers:Ch. 18.2 - Why do you suppose only symmetrical ethers are...Ch. 18.2 - How would you prepare the following ethers using a...Ch. 18.2 - Review the mechanism of oxymercuration shown in...Ch. 18.2 - How would you prepare the following ethers? Use...Ch. 18.2 - Prob. 6P Ch. 18.3 - Prob. 7P Ch. 18.3 - Write the mechanism of the acid-induced cleavage...Ch. 18.3 - Why are HI and HBr more effective than HCl in...Ch. 18.4 - What product would you expect from Claisen...

Chapter 18 Solutions