CNCT ORG CHEM 6 2020
CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Chapter 18.5, Problem 11P
Interpretation Introduction

(a)

Interpretation: The reagents that are needed to convert the given compound into acetophenone (C6H5COCH3) are to be predicted.

Concept introduction: The acylation of aromatic rings is facilitated by Friedel-Crafts acylation reaction. In this reaction, acyl chlorides are used as acylating agents, and Lewis acids like AlCl3 are used as catalyst.

Interpretation Introduction

(b)

Interpretation: The reagents that are needed to convert the given compound into acetophenone (C6H5COCH3) are to be predicted.

Concept introduction: Lithium dialkylcuprate yields ketone, when it is treated with an acyl chloride, followed by hydrolysis. This reagent is obtained from the reaction of organolithium reagent with cuprous iodide, CuI.

2R'Li+CuIR'2CuLi+LiI

Interpretation Introduction

(c)

Interpretation: The reagents that are needed to convert the given compound into acetophenone (C6H5COCH3) are to be predicted.

Concept introduction: The oxymercuration reaction is an electrophilic addition reaction that converts an alkene into an alcohol and an alkyne into a ketone. The reagents required for this reaction are [1]Hg(OAc)2;[2]H2O,Et2OorTHF.

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3. Name this ether correctly. H₁C H3C CH3 CH3 4. Show the best way to make the ether in #3 by a Williamson Ether Synthesis. Start from an alcohol or phenol. 5. Draw the structure of an example of a sulfide.
1. Which one(s) of these can be oxidized with CrO3 ? (could be more than one) a) triphenylmethanol b) 2-pentanol c) Ethyl alcohol d) CH3 2. Write in all the product(s) of this reaction. Label them as "major" or "minor". 2-methyl-2-hexanol H2SO4, heat
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds. (4 points)

Chapter 18 Solutions

CNCT ORG CHEM 6 2020

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