CNCT ORG CHEM 6 2020
CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Chapter 18.12, Problem 25P
Interpretation Introduction

(a)

Interpretation: Among the given pair of compounds, the compound which forms the higher percentage of gem-diol at equilibrium is to be identified.

Concept introduction: Carbonyl compound reacts with water in presence of acid or base forms gem-diol or hydrate. The yield of the gem-diol depends on the stability of the carbonyl compound. Electron donating groups stabilize the carbonyl compounds, decreases the amount of hydrate at equilibrium. Electron withdrawing groups destabilize the carbonyl compounds, increases the amount of hydrate at equilibrium.

Interpretation Introduction

(b)

Interpretation: Among the given pair of compounds, the compound which forms the higher percentage of gem-diol at equilibrium is to be identified.

Concept introduction: Carbonyl compound on treatment with water in presence of acid or base forms gem-diol or hydrate. The yield of the gem-diol depends on the stability of the carbonyl compound. Electron donating groups stabilize the carbonyl compounds, decreases the amount of hydrate at equilibrium. Electron withdrawing groups destabilize the carbonyl compounds, increases the amount of hydrate at equilibrium.

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Chapter 18 Solutions

CNCT ORG CHEM 6 2020

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