Chemistry: The Central Science Plus Mastering Chemistry with Pearson eText -- Access Card Package (14th Edition)
14th Edition
ISBN: 9780134292816
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 18, Problem 91IE
(a)
Interpretation Introduction
To determine: The process that is greener from the given reactions.
(b)
Interpretation Introduction
To determine: The hybridization and geometry of the carbon atoms in each
(c)
Interpretation Introduction
To determine: The method to promote the formation of isocynate intermediate in each reaction, using Le Chatelier’s principle.
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Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 18 Solutions
Chemistry: The Central Science Plus Mastering Chemistry with Pearson eText -- Access Card Package (14th Edition)
Ch. 18.1 - Prob. 18.1.1PECh. 18.1 - Prob. 18.1.2PECh. 18.1 - Prob. 18.2.1PECh. 18.1 - Practice Exercise 2 The bond energy in N2 is 941...Ch. 18.2 - Prob. 18.3.1PECh. 18.2 - Prob. 18.3.2PECh. 18 - Prob. 1DECh. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - The figure shows the three lowest regions of...
Ch. 18 - Prob. 4ECh. 18 - Where does the energy come from to evaporate the...Ch. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - The first stage of treatment at the reverse...Ch. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - Prob. 11ECh. 18 - How are the boundaries between the regions of the...Ch. 18 - Air pollution in the Mexico City metropolitan area...Ch. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - Prob. 16ECh. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Distinguish between photodissociation and...Ch. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - Do the reactions involved in ozone depletion...Ch. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Alcohol-based fuels for automobiles lead to the...Ch. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Although there are many ions in seawater, the...Ch. 18 - The Ogallala aquifer described in the Close Look...Ch. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - List the common products formed when an organic...Ch. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61AECh. 18 - Prob. 62AECh. 18 - Prob. 63AECh. 18 - Prob. 64AECh. 18 - Prob. 65AECh. 18 - Prob. 66AECh. 18 - Prob. 67AECh. 18 - Explain, using Le Châtelier’s principle, why the...Ch. 18 - Prob. 69AECh. 18 - Prob. 70AECh. 18 - Prob. 71AECh. 18 - Prob. 72AECh. 18 - Prob. 73AECh. 18 - Prob. 74AECh. 18 - Prob. 75AECh. 18 - Prob. 76AECh. 18 - Prob. 77AECh. 18 - Prob. 78IECh. 18 - Prob. 79IECh. 18 - Prob. 80IECh. 18 - Prob. 81IECh. 18 - Prob. 82IECh. 18 - Prob. 83IECh. 18 - Prob. 84IECh. 18 - 18.85 The main reason that distillation is a...Ch. 18 - Prob. 86IECh. 18 - Prob. 87IECh. 18 - Prob. 88IECh. 18 - Prob. 89IECh. 18 - Prob. 90IECh. 18 - Prob. 91IECh. 18 - Prob. 92IE
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