Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780133890686
Author: Tro
Publisher: PEARSON
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Chapter 18, Problem 87E
Interpretation Introduction
Interpretation: It is to be determine whether each of the given metal when coated onto iron, would prevent the corrosion of iron or not.
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Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
О
δα
HO-
H
-Br
δα
HO--
+
+
-Br
[B]
8+
HO-
-Br
δα
न
Chapter 18 Solutions
Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach
Ch. 18 - Prob. 1SAQCh. 18 - Q2. Which statement is true for voltaic cells?
a)...Ch. 18 - Prob. 3SAQCh. 18 - Prob. 4SAQCh. 18 - Prob. 5SAQCh. 18 - Prob. 6SAQCh. 18 - Q7. Use Table 18.1 to calculate G for the...Ch. 18 - Prob. 8SAQCh. 18 - Prob. 9SAQCh. 18 - Prob. 10SAQ
Ch. 18 - Prob. 11SAQCh. 18 - Prob. 12SAQCh. 18 - Prob. 13SAQCh. 18 - Prob. 14SAQCh. 18 - Q15. Which metal can be used as a sacrificial...Ch. 18 - 1. In electrochemistry, spontaneous redox...Ch. 18 - Prob. 2ECh. 18 - Prob. 3ECh. 18 - Prob. 4ECh. 18 - Prob. 5ECh. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - Prob. 8ECh. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - Prob. 11ECh. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - 15. Is a spontaneous redox reaction obtained by...Ch. 18 - 16. How can Table 19.1 be used to predict whether...Ch. 18 - 17. Explain why , , and K are all interrelated.
Ch. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - 23. What are the anode and cathode reactions in a...Ch. 18 - Prob. 24ECh. 18 - 25. What is a fuel cell? What is the most common...Ch. 18 - Prob. 26ECh. 18 - 27. List some applications of electrolysis.
Ch. 18 - Prob. 28ECh. 18 - 29. What species is oxidized, and what species is...Ch. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Balance each redox reaction occurring in acidic...Ch. 18 - 38. Balance each redox reaction occurring in...Ch. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - 41. Balance each redox reaction occurring in basic...Ch. 18 - Prob. 42ECh. 18 - 43. Sketch a voltaic cell for each redox reaction....Ch. 18 - 44. Sketch a voltaic cell for each redox reaction....Ch. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - 47. Consider the voltaic cell:
a. Determine the...Ch. 18 - 48. Consider the voltaic cell:
a. Determine the...Ch. 18 - 49. Use line notation to represent each...Ch. 18 - 50. Use line notation to represent each...Ch. 18 - Make a sketch of the voltaic cell represented by...Ch. 18 - 52. Make a sketch of the voltaic cell represented...Ch. 18 - 53. Determine whether or not each redox reaction...Ch. 18 - 54. Determine whether or not each redox reaction...Ch. 18 - 55. Which metal could you use to reduce Mn2+ ions...Ch. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61ECh. 18 - 62. Calculate for each balanced redox reaction...Ch. 18 - Prob. 63ECh. 18 - 64. Which metal is the best reducing agent?
a....Ch. 18 - 65. Use tabulated electrode potentials to...Ch. 18 - Prob. 66ECh. 18 - 67. Calculate the equilibrium constant for each of...Ch. 18 - 68. Calculate the equilibrium constant for each of...Ch. 18 - Prob. 69ECh. 18 - Prob. 70ECh. 18 - Prob. 71ECh. 18 - 72. Calculate and for a redox reaction with n =...Ch. 18 - 73. A voltaic cell employs the following redox...Ch. 18 - 74. A voltaic cell employs the redox reaction:
2...Ch. 18 - 75. An electrochemical cell is based on these two...Ch. 18 - Prob. 76ECh. 18 - 77. A voltaic cell consists of a Zn/Zn2+ half-cell...Ch. 18 - 78. A voltaic cell consists of a Pb/Pb2+ half-cell...Ch. 18 - Prob. 79ECh. 18 - Prob. 80ECh. 18 - 81. A concentration cell consists of two Sn/Sn2+...Ch. 18 - Prob. 82ECh. 18 - 83. Determine the optimum mass ratio of Zn to MnO2...Ch. 18 - 84. What mass of lead sulfate is formed in a...Ch. 18 - 85. Refer to the tabulated values of in Appendix...Ch. 18 - 86. Refer to the tabulated values of in Appendix...Ch. 18 - Prob. 87ECh. 18 - Prob. 88ECh. 18 - Prob. 89ECh. 18 - Prob. 90ECh. 18 - 91. Write equations for the half-reactions that...Ch. 18 - Prob. 92ECh. 18 - 93. Write equations for the half-reactions that...Ch. 18 - 94. What products are obtained in the electrolysis...Ch. 18 - 95. Write equations for the half-reactions that...Ch. 18 - Prob. 96ECh. 18 - 97. Make a sketch of an electrolysis cell that...Ch. 18 - Prob. 98ECh. 18 - Prob. 99ECh. 18 - Prob. 100ECh. 18 - Prob. 101ECh. 18 - Prob. 102ECh. 18 - 105103. Consider the unbalanced redox...Ch. 18 - Prob. 104ECh. 18 - 107. Consider the molecular views of an Al strip...Ch. 18 - 106. Consider the molecular view of an...Ch. 18 - Prob. 107ECh. 18 - Prob. 108ECh. 18 - Prob. 109ECh. 18 - Prob. 110ECh. 18 - Prob. 111ECh. 18 - Prob. 112ECh. 18 - Prob. 113ECh. 18 - Prob. 114ECh. 18 - Prob. 115ECh. 18 - Prob. 116ECh. 18 - 119. The Ksp of CuI is 1.1 × 10–12. Find Ecell for...Ch. 18 - 120. The Ksp of Zn(OH)2 is 1.8 × 10–14. Find Ecell...Ch. 18 - 121. Calculate and K for each reaction.
a. The...Ch. 18 - Prob. 120ECh. 18 - Prob. 121ECh. 18 - Prob. 122ECh. 18 - Prob. 123ECh. 18 - Prob. 124ECh. 18 - Prob. 125ECh. 18 - Prob. 126ECh. 18 - Prob. 127ECh. 18 - 130. To what pH should you adjust a standard...Ch. 18 - 131. Suppose a hydrogen–oxygen fuel-cell generator...Ch. 18 - 132. A voltaic cell designed to measure [Cu2+] is...Ch. 18 - 133. The surface area of an object to be gold...Ch. 18 - Prob. 132ECh. 18 - Prob. 133ECh. 18 - Prob. 134ECh. 18 - Prob. 135ECh. 18 - Prob. 136ECh. 18 - Prob. 137ECh. 18 - 140. A redox reaction employed in an...Ch. 18 - 141. A redox reaction has an equilibrium constant...
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