Explanation (a) We have the following redox reaction : I − ( a q ) + N O 2 − → I 2 ( s ) + N O ( g ) Step 1: Separate the overall reaction into two half-reactions: one for oxidation and one for reduction. O x i d a t i o n : I − ( a q ) → I 2 ( s ) Reduction : N O 2 − ( s ) → N O ( g ) Step 2: Balance the elements, excluding H, O. O x i d a t i o n : 2 I − ( a q ) → I 2 ( s ) Reduction : N O 2 − ( s ) → N O ( g ) Step 3: Balance the elements H, O. O x i d a t i o n : 2 I − ( a q ) → I 2 ( s ) Reduction : N O 2 − ( s ) + 2 H + ( a q ) → N O ( g ) + H 2 O ( l ) In these half-reactions, all elements are balanced, including H, O. Hence, in the next step we need to balance the charge. Step 4: Balance each half-reaction with respect to charge by adding electrons. O x i d a t i o n : 2 I − ( a q ) → I 2 ( s ) + 2 e − Reduction : N O 2 − ( s ) + 2 H + ( a q ) + 1 e − → N O ( g ) + H 2 O ( l ) Step 5: Make the number of electrons in both half-reactions equal by multiplying one or both half reactions by a small whole number. O x i d a t i o n : [ 2 I − ( a q ) → I 2 ( s ) + 2 e − ] × 1 Reduction : [ N O 2 − ( s ) + 2 H + ( a q ) + 1 e − → N O ( g ) + H 2 O ( l ) ] × 2 Add these two reactions to get the balanced reaction. 2 N O 2 − ( s ) + 4 H + ( a q ) + 2 I − ( a q ) → 2 N O ( g ) + 2 H 2 O ( l ) + I 2 ( s ) (b) We have the following redox reaction: C l O 4 − ( a q ) + C l − ( a q ) → C l O 3 − ( a q ) + C l 2 ( g ) Step 1: Separate the overall reaction into two half-reactions: one for oxidation and one for reduction. O x i d a t i o n : C l − ( a q ) → C l 2 ( s ) Reduction : C l O 4 − ( a q ) → C l O 3 − ( a q ) Step 2: Balance the elements, excluding H, O. O x i d a t i o n : 2 C l − ( a q ) → C l 2 ( s ) Reduction : C l O 4 − ( a q ) → C l O 3 − ( a q ) Step 3: Balance the elements H, O. O x i d a t i o n : 2 C l − ( a q ) → C l 2 ( s ) Reduction : C l O 4 − ( a q ) + 2 H + ( a q ) → C l O 3 − ( a q ) + H 2 O ( l ) In these half-reactions, all elements are balanced, including H, O

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

3rd Edition

ISBN: 9780133890686

Author: Tro

Publisher: PEARSON

See similar textbooks

Videos

Question

Chapter 18, Problem 40E

Interpretation Introduction

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Chapter 18, Problem 39E

Chapter 18, Problem 41E

Students have asked these similar questions

Steps and explanation please

Steps and explanation please. Add how to solve or target similar problems.

Chapter 18 Solutions

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

Ch. 18 - Prob. 1SAQ Ch. 18 - Q2. Which statement is true for voltaic cells? a)...Ch. 18 - Prob. 3SAQ Ch. 18 - Prob. 4SAQ Ch. 18 - Prob. 5SAQ Ch. 18 - Prob. 6SAQ Ch. 18 - Q7. Use Table 18.1 to calculate G for the...Ch. 18 - Prob. 8SAQ Ch. 18 - Prob. 9SAQ Ch. 18 - Prob. 10SAQ

Ch. 18 - Prob. 11SAQ Ch. 18 - Prob. 12SAQ Ch. 18 - Prob. 13SAQ Ch. 18 - Prob. 14SAQ Ch. 18 - Q15. Which metal can be used as a sacrificial...Ch. 18 - 1. In electrochemistry, spontaneous redox...Ch. 18 - Prob. 2E Ch. 18 - Prob. 3E Ch. 18 - Prob. 4E Ch. 18 - Prob. 5E Ch. 18 - Prob. 6E Ch. 18 - Prob. 7E Ch. 18 - Prob. 8E Ch. 18 - Prob. 9E Ch. 18 - Prob. 10E Ch. 18 - Prob. 11E Ch. 18 - Prob. 12E Ch. 18 - Prob. 13E Ch. 18 - Prob. 14E Ch. 18 - 15. Is a spontaneous redox reaction obtained by...Ch. 18 - 16. How can Table 19.1 be used to predict whether...Ch. 18 - 17. Explain why , , and K are all interrelated. Ch. 18 - Prob. 18E Ch. 18 - Prob. 19E Ch. 18 - Prob. 20E Ch. 18 - Prob. 21E Ch. 18 - Prob. 22E Ch. 18 - 23. What are the anode and cathode reactions in a...Ch. 18 - Prob. 24E Ch. 18 - 25. What is a fuel cell? What is the most common...Ch. 18 - Prob. 26E Ch. 18 - 27. List some applications of electrolysis. Ch. 18 - Prob. 28E Ch. 18 - 29. What species is oxidized, and what species is...Ch. 18 - Prob. 30E Ch. 18 - Prob. 31E Ch. 18 - Prob. 32E Ch. 18 - Prob. 33E Ch. 18 - Prob. 34E Ch. 18 - Prob. 35E Ch. 18 - Prob. 36E Ch. 18 - Balance each redox reaction occurring in acidic...Ch. 18 - 38. Balance each redox reaction occurring in...Ch. 18 - Prob. 39E Ch. 18 - Prob. 40E Ch. 18 - 41. Balance each redox reaction occurring in basic...Ch. 18 - Prob. 42E Ch. 18 - 43. Sketch a voltaic cell for each redox reaction....Ch. 18 - 44. Sketch a voltaic cell for each redox reaction....Ch. 18 - Prob. 45E Ch. 18 - Prob. 46E Ch. 18 - 47. Consider the voltaic cell: a. Determine the...Ch. 18 - 48. Consider the voltaic cell: a. Determine the...Ch. 18 - 49. Use line notation to represent each...Ch. 18 - 50. Use line notation to represent each...Ch. 18 - Make a sketch of the voltaic cell represented by...Ch. 18 - 52. Make a sketch of the voltaic cell represented...Ch. 18 - 53. Determine whether or not each redox reaction...Ch. 18 - 54. Determine whether or not each redox reaction...Ch. 18 - 55. Which metal could you use to reduce Mn2+ ions...Ch. 18 - Prob. 56E Ch. 18 - Prob. 57E Ch. 18 - Prob. 58E Ch. 18 - Prob. 59E Ch. 18 - Prob. 60E Ch. 18 - Prob. 61E Ch. 18 - 62. Calculate for each balanced redox reaction...Ch. 18 - Prob. 63E Ch. 18 - 64. Which metal is the best reducing agent? a....Ch. 18 - 65. Use tabulated electrode potentials to...Ch. 18 - Prob. 66E Ch. 18 - 67. Calculate the equilibrium constant for each of...Ch. 18 - 68. Calculate the equilibrium constant for each of...Ch. 18 - Prob. 69E Ch. 18 - Prob. 70E Ch. 18 - Prob. 71E Ch. 18 - 72. Calculate and for a redox reaction with n =...Ch. 18 - 73. A voltaic cell employs the following redox...Ch. 18 - 74. A voltaic cell employs the redox reaction: 2...Ch. 18 - 75. An electrochemical cell is based on these two...Ch. 18 - Prob. 76E Ch. 18 - 77. A voltaic cell consists of a Zn/Zn2+ half-cell...Ch. 18 - 78. A voltaic cell consists of a Pb/Pb2+ half-cell...Ch. 18 - Prob. 79E Ch. 18 - Prob. 80E Ch. 18 - 81. A concentration cell consists of two Sn/Sn2+...Ch. 18 - Prob. 82E Ch. 18 - 83. Determine the optimum mass ratio of Zn to MnO2...Ch. 18 - 84. What mass of lead sulfate is formed in a...Ch. 18 - 85. Refer to the tabulated values of in Appendix...Ch. 18 - 86. Refer to the tabulated values of in Appendix...Ch. 18 - Prob. 87E Ch. 18 - Prob. 88E Ch. 18 - Prob. 89E Ch. 18 - Prob. 90E Ch. 18 - 91. Write equations for the half-reactions that...Ch. 18 - Prob. 92E Ch. 18 - 93. Write equations for the half-reactions that...Ch. 18 - 94. What products are obtained in the electrolysis...Ch. 18 - 95. Write equations for the half-reactions that...Ch. 18 - Prob. 96E Ch. 18 - 97. Make a sketch of an electrolysis cell that...Ch. 18 - Prob. 98E Ch. 18 - Prob. 99E Ch. 18 - Prob. 100E Ch. 18 - Prob. 101E Ch. 18 - Prob. 102E Ch. 18 - 105103. Consider the unbalanced redox...Ch. 18 - Prob. 104E Ch. 18 - 107. Consider the molecular views of an Al strip...Ch. 18 - 106. Consider the molecular view of an...Ch. 18 - Prob. 107E Ch. 18 - Prob. 108E Ch. 18 - Prob. 109E Ch. 18 - Prob. 110E Ch. 18 - Prob. 111E Ch. 18 - Prob. 112E Ch. 18 - Prob. 113E Ch. 18 - Prob. 114E Ch. 18 - Prob. 115E Ch. 18 - Prob. 116E Ch. 18 - 119. The Ksp of CuI is 1.1 × 10–12. Find Ecell for...Ch. 18 - 120. The Ksp of Zn(OH)2 is 1.8 × 10–14. Find Ecell...Ch. 18 - 121. Calculate and K for each reaction. a. The...Ch. 18 - Prob. 120E Ch. 18 - Prob. 121E Ch. 18 - Prob. 122E Ch. 18 - Prob. 123E Ch. 18 - Prob. 124E Ch. 18 - Prob. 125E Ch. 18 - Prob. 126E Ch. 18 - Prob. 127E Ch. 18 - 130. To what pH should you adjust a standard...Ch. 18 - 131. Suppose a hydrogen–oxygen fuel-cell generator...Ch. 18 - 132. A voltaic cell designed to measure [Cu2+] is...Ch. 18 - 133. The surface area of an object to be gold...Ch. 18 - Prob. 132E Ch. 18 - Prob. 133E Ch. 18 - Prob. 134E Ch. 18 - Prob. 135E Ch. 18 - Prob. 136E Ch. 18 - Prob. 137E Ch. 18 - 140. A redox reaction employed in an...Ch. 18 - 141. A redox reaction has an equilibrium constant...

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.