The given compounds can be synthesized by aldol condensation. Concept introduction: An aldol condensation is the condensation of two aldehydes , two ketones or one aldehyde and one ketone followed by an acid-catalyzed or base-catalyzed dehydration to form α - β unsaturated carbonyl compound. If the two carbonyl compounds differ then the reaction is known as cross-aldol condensation.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 71P

Interpretation Introduction

Interpretation:

The given compounds can be synthesized by aldol condensation.

Concept introduction:

An aldol condensation is the condensation of two aldehydes, two ketones or one aldehyde and one ketone followed by an acid-catalyzed or base-catalyzed dehydration to form α-β unsaturated carbonyl compound. If the two carbonyl compounds differ then the reaction is known as cross-aldol condensation.

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Gramicidin A can adopt more than one structure; NMR spectroscopy has revealed an “end-to-end” dimer form, and x-ray crystallography has revealed an “anti-parallel double- helical” form. Briefly outline and describe an experimentalapproach/strategy to investigate WHICH configuration (“end-to-end dimer” vs “anti-paralleldouble helical”) gramicidin adopts in an actual lipid bilayer.

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 71P

Interpretation Introduction

Interpretation:

The given compounds can be synthesized by aldol condensation.

Concept introduction:

An aldol condensation is the condensation of two aldehydes, two ketones or one aldehyde and one ketone followed by an acid-catalyzed or base-catalyzed dehydration to form α-β unsaturated carbonyl compound. If the two carbonyl compounds differ then the reaction is known as cross-aldol condensation.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 71P

Interpretation Introduction

Interpretation:

The given compounds can be synthesized by aldol condensation.

Concept introduction:

An aldol condensation is the condensation of two aldehydes, two ketones or one aldehyde and one ketone followed by an acid-catalyzed or base-catalyzed dehydration to form α-β unsaturated carbonyl compound. If the two carbonyl compounds differ then the reaction is known as cross-aldol condensation.

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 71P

Interpretation Introduction