Bundle: Introductory Chemistry: A Foundation, 8th + OWLv2 6-Months Printed Access Card
8th Edition
ISBN: 9781305367333
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 18, Problem 69AP
Interpretation Introduction
Interpretation:
The term corresponding to the given blank is to be stated.
The sum of the oxidation states of the atoms in a polyatomic ion is equal to the overall of ________the ion.
Concept Introduction:
Oxidation state is represented as a number that is given to an atom when it gain or lose some electrons. If an atom loses an electron then the oxidation state of the atom gets increased by one. If an atom gains an electron then the oxidation state of the atom gets decreased by one.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 18 Solutions
Bundle: Introductory Chemistry: A Foundation, 8th + OWLv2 6-Months Printed Access Card
Ch. 18.1 - Prob. 18.1SCCh. 18.2 - Prob. 1CTCh. 18.2 - Prob. 18.2SCCh. 18.3 - Prob. 18.3SCCh. 18.4 - Prob. 18.4SCCh. 18.7 - Prob. 1CTCh. 18 - Sketch a galvanic cell, and explain how it works....Ch. 18 - Prob. 2ALQCh. 18 - Which of the following are oxidation-reduction...Ch. 18 - Prob. 4ALQ
Ch. 18 - Prob. 5ALQCh. 18 - Prob. 6ALQCh. 18 - In balancing oxidation-reduction equations, why is...Ch. 18 - What does it mean for a substance to be oxidized?...Ch. 18 - Label the following parts of the galvanic cell....Ch. 18 - Prob. 1QAPCh. 18 - Prob. 2QAPCh. 18 - For each of the following oxidation-reduction...Ch. 18 - For each of the following oxidation-reduction...Ch. 18 - For each of the following oxidation-reduction...Ch. 18 - Prob. 6QAPCh. 18 - Prob. 7QAPCh. 18 - Prob. 8QAPCh. 18 - Explain why, although it is not an ionic compound,...Ch. 18 - Prob. 10QAPCh. 18 - Prob. 11QAPCh. 18 - Prob. 12QAPCh. 18 - Prob. 13QAPCh. 18 - . Assign oxidation states to all of the atoms in...Ch. 18 - Prob. 15QAPCh. 18 - Prob. 16QAPCh. 18 - . What is the oxidation state of chlorine in each...Ch. 18 - . What is the oxidation state of manganese in each...Ch. 18 - Prob. 19QAPCh. 18 - Assign oxidation states to all of the atoms in...Ch. 18 - Prob. 21QAPCh. 18 - Prob. 22QAPCh. 18 - Prob. 23QAPCh. 18 - Prob. 24QAPCh. 18 - Prob. 25QAPCh. 18 - Prob. 26QAPCh. 18 - . Does an oxidizing agent donate or accept...Ch. 18 - Prob. 28QAPCh. 18 - Prob. 29QAPCh. 18 - Prob. 30QAPCh. 18 - Prob. 31QAPCh. 18 - Prob. 32QAPCh. 18 - Prob. 33QAPCh. 18 - Prob. 34QAPCh. 18 - Prob. 35QAPCh. 18 - Prob. 36QAPCh. 18 - Prob. 37QAPCh. 18 - Prob. 38QAPCh. 18 - Prob. 39QAPCh. 18 - Prob. 40QAPCh. 18 - Prob. 41QAPCh. 18 - Prob. 42QAPCh. 18 - Prob. 43QAPCh. 18 - Prob. 44QAPCh. 18 - . Balance each of the following...Ch. 18 - Prob. 46QAPCh. 18 - . Iodide ion, I- , is one of the most easily...Ch. 18 - Prob. 48QAPCh. 18 - Prob. 49QAPCh. 18 - Prob. 50QAPCh. 18 - . In which direction do electrons flow in a...Ch. 18 - Prob. 52QAPCh. 18 - . Consider the oxidation-reduction reaction...Ch. 18 - . Consider the oxidation—reduction reaction...Ch. 18 - Prob. 55QAPCh. 18 - Prob. 56QAPCh. 18 - Prob. 57QAPCh. 18 - Prob. 58QAPCh. 18 - Prob. 59QAPCh. 18 - Prob. 60QAPCh. 18 - Prob. 61QAPCh. 18 - Prob. 62QAPCh. 18 - . Although aluminum is one of the most abundant...Ch. 18 - . The “Chemistry in Focus” segment Water-Powered...Ch. 18 - Prob. 65APCh. 18 - Prob. 66APCh. 18 - Prob. 67APCh. 18 - Prob. 68APCh. 18 - Prob. 69APCh. 18 - Prob. 70APCh. 18 - Prob. 71APCh. 18 - Prob. 72APCh. 18 - Prob. 73APCh. 18 - . To obtain useful electrical energy from an...Ch. 18 - Prob. 75APCh. 18 - Prob. 76APCh. 18 - Prob. 77APCh. 18 - Prob. 78APCh. 18 - . The “pressure” on electrons to flow from one...Ch. 18 - Prob. 80APCh. 18 - Prob. 81APCh. 18 - Prob. 82APCh. 18 - Prob. 83APCh. 18 - . For each of the following unbalanced...Ch. 18 - Prob. 85APCh. 18 - Prob. 86APCh. 18 - Prob. 87APCh. 18 - . Balance each of the following...Ch. 18 - . Balance each of the following...Ch. 18 - . For each of the following oxidation-reduction...Ch. 18 - . For each of the following oxidation-reduction...Ch. 18 - . Assign oxidation sates to all of the atoms in...Ch. 18 - . Assign oxidation states to all of the atoms in...Ch. 18 - Prob. 94APCh. 18 - Prob. 95APCh. 18 - . Assign oxidation states to all of the atoms in...Ch. 18 - Prob. 97APCh. 18 - . In each of the following reactions, identify...Ch. 18 - . Balance each of the following half-reactions....Ch. 18 - Prob. 100APCh. 18 - Prob. 101APCh. 18 - Prob. 102APCh. 18 - . Consider the oxidation—reduction reaction...Ch. 18 - Prob. 104APCh. 18 - Prob. 105CP
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