Physics (5th Edition)
5th Edition
ISBN: 9780134051802
Author: Walker
Publisher: PEARSON
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Chapter 18, Problem 57PCE
(a)
To determine
The required mechanical work of the refrigerator.
(b)
To determine
The money saved during
92 − day
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6. We used the constant volume heat capacity, Cv, when we talked about
thermodynamic cycles. It acts as a proportionality constant between energy and
temperature: dU = C₁dT.
You can also define a heat capacity for constant pressure processes, Cp. You can think
of enthalpy playing a similar role to energy, but for constant pressure processes
δαρ
C = (37) - Sup
Ср
ат
P
=
ат
Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy
and Cp for an ideal gas.
Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt
= 41°C. Reversible melting experiments indicate that
at Tm
AHm=37.7 kJ mol-1. Calculate:
A. The entropy of melting, ASm-
B. The Gibbs free energy of melting, AGm-
C. Does the membrane become more or less ordered upon melting?
D. There are 32 rotatable CH2
CH2 bonds in each molecule that can rotate more freely if the
membrane melts. What is the increase in multiplicity on melting a mole of bonds?
Chapter 18 Solutions
Physics (5th Edition)
Ch. 18.1 - System 1 is at 0 C and system 2 is at 0 F. If...Ch. 18.2 - Enhance Your Understanding (Answers given at the...Ch. 18.3 - Enhance Your Understanding (Answers given at the...Ch. 18.4 - Enhance Your Understanding (Answers given at the...Ch. 18.5 - Enhance Your Understanding (Answers given at the...Ch. 18.6 - Enhance Your Understanding (Answers given at the...Ch. 18.7 - Enhance Your Understanding (Answers given at the...Ch. 18.8 - Enhance Your Understanding (Answers given at the...Ch. 18.9 - Enhance Your Understanding (Answers given at the...Ch. 18.10 - Enhance Your Understanding (Answer given at the...
Ch. 18 - Prob. 1CQCh. 18 - Heat is added to a substance. Is it safe to...Ch. 18 - Are there thermodynamic processes in which all the...Ch. 18 - An ideal gas is held in an insulated container at...Ch. 18 - Prob. 5CQCh. 18 - Which law of thermodynamics would be violated if...Ch. 18 - Heat engines always give off a certain amount of...Ch. 18 - Prob. 8CQCh. 18 - Which law of thermodynamics is most pertinent to...Ch. 18 - Which has more entropy: (a) popcorn kernels, or...Ch. 18 - Prob. 1PCECh. 18 - A gas expands, doing 100 J of work. How much heat...Ch. 18 - A swimmer does 7.7 105 J of work and gives off...Ch. 18 - When 1310 J of heat are added to one mole of an...Ch. 18 - Three different processes act on a system. (a) In...Ch. 18 - A container holds a gas consisting of 2.85 moles...Ch. 18 - The Charge on Adhesive Tape When adhesive tape is...Ch. 18 - Predict/Calculate One mole of an ideal monatomic...Ch. 18 - Prob. 9PCECh. 18 - A cylinder contains 4.0 moles of a monatomic gas...Ch. 18 - An ideal gas is taken through the three processes...Ch. 18 - Figure 18-26 shows three different multistep...Ch. 18 - Prob. 13PCECh. 18 - An ideal gas is compressed at constant pressure to...Ch. 18 - As an ideal gas expands at constant pressure from...Ch. 18 - A system consisting of an ideal gas at the...Ch. 18 - Prob. 17PCECh. 18 - (a) Find the work done by a monatomic ideal gas as...Ch. 18 - Prob. 19PCECh. 18 - Predict/Calculate If 9.50 moles of a monatomic...Ch. 18 - Suppose 118 moles of a monatomic ideal gas undergo...Ch. 18 - A weather balloon contains an ideal gas and has a...Ch. 18 - Prob. 23PCECh. 18 - During an adiabatic process, the temperature of...Ch. 18 - An ideal gas follows the three-part process shown...Ch. 18 - With the pressure held constant at 260 kPa, 43 mol...Ch. 18 - Prob. 27PCECh. 18 - A system expands by 0.75 m3 at a constant pressure...Ch. 18 - Prob. 29PCECh. 18 - A certain amount of a monatomic ideal gas...Ch. 18 - An ideal gas doubles its volume in one of three...Ch. 18 - Predict/Explain You plan to add a certain amount...Ch. 18 - Find the amount of heat needed to increase the...Ch. 18 - (a) If 585 J of heat are added to 49 moles of a...Ch. 18 - A system consists of 3.5 mol of an ideal monatomic...Ch. 18 - Find the change in temperature if 170 J of heat...Ch. 18 - Gasoline Ignition Consider a short time span just...Ch. 18 - Prob. 38PCECh. 18 - Prob. 39PCECh. 18 - A monatomic ideal gas is held in a thermally...Ch. 18 - Consider the expansion of 60.0 moles of a...Ch. 18 - A Carnot engine can be operated with one of the...Ch. 18 - What is the efficiency of an engine that exhausts...Ch. 18 - An engine receives 660 J of heat from a hot...Ch. 18 - A Carnot engine operates between the temperatures...Ch. 18 - A nuclear power plant has a reactor that produces...Ch. 18 - At a coal-burning power plant a steam turbine is...Ch. 18 - Predict/Calculate A portable generator produces...Ch. 18 - Predict/Calculate The efficiency of a particular...Ch. 18 - During each cycle a reversible engine absorbs 3100...Ch. 18 - Prob. 51PCECh. 18 - The operating temperatures for a Carnot engine are...Ch. 18 - A certain Carnot engine takes in the heat Qh and...Ch. 18 - Predict/Explain (a) If the temperature in the...Ch. 18 - The refrigerator in your kitchen does 490 J of...Ch. 18 - A refrigerator with a coefficient of performance...Ch. 18 - Prob. 57PCECh. 18 - Prob. 58PCECh. 18 - An air conditioner is used to keep the interior of...Ch. 18 - A reversible refrigerator has a coefficient of...Ch. 18 - A freezer has a coefficient of performance equal...Ch. 18 - Predict/Explain (a) If you rub your hands...Ch. 18 - Predict/Explain (a) An ideal gas is expanded...Ch. 18 - Predict/Explain (a) A gas is expanded reversibly...Ch. 18 - Find the change in entropy when 1.85 kg of water...Ch. 18 - Determine the change in entropy that occurs when...Ch. 18 - Prob. 67PCECh. 18 - On a cold winters day heat leaks slowly out of a...Ch. 18 - An 88-kg parachutist descends through a vertical...Ch. 18 - Predict/Calculate Consider the air-conditioning...Ch. 18 - A heat engine operates between a high-temperature...Ch. 18 - It can be shown that as a mass m with specific...Ch. 18 - Prob. 73GPCh. 18 - Figure 18-34 Problem 74 74 CE An ideal gas has...Ch. 18 - The heat that goes into a particular Carnot engine...Ch. 18 - Predict/Calculate Consider 132 moles of a...Ch. 18 - Prob. 77GPCh. 18 - Prob. 78GPCh. 18 - Predict/Calculate Engine A has an efficiency of...Ch. 18 - Nuclear Versus Natural Gas Energy Because of...Ch. 18 - A freezer with a coefficient of performance of...Ch. 18 - Entropy and the Sun The surface of the Sun has a...Ch. 18 - Prob. 83GPCh. 18 - A cylinder with a movable piston holds 2.95 mol of...Ch. 18 - Making Ice You place 0.410 kg of cold water inside...Ch. 18 - An inventor claims a new cyclic engine that uses...Ch. 18 - Predict/Calculate A small dish containing 530 g of...Ch. 18 - Predict/Calculate An ideal gas is taken through...Ch. 18 - One mole of an ideal monatomic gas follows the...Ch. 18 - When a heat Q is added to a monatomic ideal gas at...Ch. 18 - The Carnot Cycle Figure 18-36 shows an example of...Ch. 18 - A Carnot engine and a Carnot refrigerator operate...Ch. 18 - Prob. 93PPCh. 18 - Energy from the Ocean Whenever two objects are at...Ch. 18 - Prob. 95PPCh. 18 - Energy from me Ocean Whenever two objects are at...Ch. 18 - Predict/Calculate Referring to Example 18-21...Ch. 18 - Predict/Calculate Referring to Example 18-21...
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- 5. Heat capacity often has a temperature dependence for real molecules, particularly if you go over a large temperature range. The heat capacity for liquid n-butane can be fit to the equation Cp(T) = a + bT where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K) to its boiling point (T₁ = 270 K). A. Compute AH for heating butane from 170 K to 270 K. B. Compute AS for the same temperature range.arrow_forward4. How much energy must be transferred as heat to cause the quasi-static isothermal expansion of one mole of an ideal gas at 300 K from PA = 1 bar to PB = 0.5 bar? A. What is VA? B. What is VB? C. What is AU for the process? D. What is AH for the process? E. What is AS for the process?arrow_forward1. The diagram shows the tube used in the Thomson experiment. a. State the KE of the electrons. b. Draw the path of the electron beam in the gravitational field of the earth. C. If the electric field directed upwards, deduce the direction of the magnetic field so it would be possible to balance the forces. electron gun 1KVarrow_forward
- as a hiker in glacier national park, you need to keep the bears from getting at your food supply. You find a campground that is near an outcropping of ice. Part of the outcropping forms a feta=51.5* slopeup that leads to a verticle cliff. You decide that this is an idea place to hang your food supply out of bear reach. You put all of your food into a burlap sack, tie a rope to the sack, and then tie a bag full of rocks to the other end of the rope to act as an anchor. You currently have 18.5 kg of food left for the rest of your trip, so you put 18.5 kg of rocks in the anchor bag to balance it out. what happens when you lower the food bag over the edge and let go of the anchor bag? Determine the acceleration magnitude a of the two-bag system when you let go of the anchor bag?arrow_forward2. A thin Nichrome wire is used in an experiment to test Ohm's law using a power supply ranging from 0 to 12 V in steps of 2 V. Why isn't the graph of I vs V linear? 1. Nichrome wire does obey Ohm's law. Explain how that can that be true given the results abovearrow_forward1. The average KE and temperature in Kelvin of the molecules of a gas are related by the equation KE = 3/2 KT where k is the Boltzmann constant 1.38 x 10 m² kg s². The diagram shows the energy levels for a Hydrogen atom. Energy/eV 0.00 -1.51 3.39 13.58 Use this information to show that Hydrogen at room temperature will not emit light. 2. When hydrogen burns in oxygen 241.8 kJ of energy are released per mole. Show that this reaction can produce light.arrow_forward
- 3. By using the fact that around any closed loop the sum of the EMFS = the sum of the PDs. Write equations for the two loops shown in the cct below. 40 ΔΩ I₂ 4V (loop1 20 (loop2) 2v I+12 Use these equations to show that the current flowing through the 20 resistor is 0.75Aarrow_forward5. A potential divider circuit is made by stretching a 1 m long wire with a resistance of 0.1 per cm from A to B as shown. 8V A 100cm B sliding contact 5Ω A varying PD is achieved across the 5 Q resistor by moving the slider along the resistance wire. Calculate the distance from A when the PD across the 5 Q resistor is 6 V.arrow_forward4. A voltmeter with resistance 10 kQ is used to measure the pd across the 1 kQ resistor in the circuit below. 6V 5ΚΩ 1ΚΩ V Calculate the percentage difference between the value with and without the voltmeter.arrow_forward
- 1. A 9V battery with internal resistance 5 2 is connected to a 100 2 resistor. Calculate: a. the Power dissipated in the 100 2 resistor b. The heat generated per second inside the battery. C. The rate of converting chemical to electrical energy by the battery. 2. A 230 V kettle is rated at 1800 W. Calculate the resistance of the heating element.arrow_forward2. If each of the resistors in the circuit below has resistance R show that the total resistance between A and B is 5R/11 A Barrow_forward1. At 0°C a steel cable is 1km long and 1cm diameter when it is heated it expands and its resistivity increases. Calculate the change in resistance of the cable as it is heated from 0-20°C The temperature coefficient of resistance a, gives the fractional increase in resistance per °C. So increase in resistance AR = Ra.AT Where R, is the resistance at 0°C For steel a, 0.003 °C The coefficient of linear expansion a- gives the fractional increase in length per °C temperature rise. So increase in Length AL La-AT Where L, is the length at 0°C For steel a₁ = 12 x 10 °C-1 The resistivity of steel at 0°C = 1.2 x 10 Qmarrow_forward
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