Organic Chemistry, 12e Study Guide/Student Solutions Manual
Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 18, Problem 31P
Interpretation Introduction

Interpretation:

The mechanism of the given reaction is to be suggested and the explanation of the formation of the products, when (CH3)2CHCHO and Ba(OH)2/H2O are heated in a sealed tube, is to be provided.

Concept Introduction:

▸ Cannizzaro reaction is the oxidation and reduction reaction in a strong base.

▸ The Cannizzaro reaction is a process in which carbonyl compound without alpha hydrogens form into carboxylic acid and an alcohol.

▸ An aldol condensation is the condensation reaction in which an enolate reacts with the carbonyl compound to form a βhydroxyketone.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

Chapter 18 Solutions

Organic Chemistry, 12e Study Guide/Student Solutions Manual

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