Introductory Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (6th Edition) (New Chemistry Titles from Niva Tro)
6th Edition
ISBN: 9780134290812
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 18, Problem 23E
Interpretation Introduction
Interpretation:
The generic structure of ethers with its examples.
Concept introduction:
The ethers are the organic compounds that contain ether group. Ether group is a group in which an oxygen is connected to two alkyl or aryl groups. The structure of ethers is similar to the structure of water.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 18 Solutions
Introductory Chemistry Plus Mastering Chemistry with Pearson eText -- Access Card Package (6th Edition) (New Chemistry Titles from Niva Tro)
Ch. 18 - Prob. 1SAQCh. 18 - Q2. What is the correct formula for the alkane...Ch. 18 - Which structure is not an isomer of...Ch. 18 - Prob. 4SAQCh. 18 - Prob. 5SAQCh. 18 - Name the compound. a. 2-methyI-3-pentene b....Ch. 18 - Prob. 7SAQCh. 18 - Prob. 8SAQCh. 18 - Prob. 9SAQCh. 18 - Prob. 10SAQ
Ch. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - Prob. 3ECh. 18 - 4. What is vitalism? How was vitalism usurped?
Ch. 18 - Prob. 5ECh. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - Prob. 8ECh. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - 11. Explain the difference between n-alkanes and...Ch. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - What are alkane substitution reactions? Provide an...Ch. 18 - 17. What is an alkene addition reaction? Provide...Ch. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - 21. What is the generic structure of alcohols?...Ch. 18 - Prob. 22ECh. 18 - Prob. 23ECh. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Prob. 43ECh. 18 - Name each alkane.Ch. 18 - Prob. 45ECh. 18 - 46. Draw a structure for each alkane.
...Ch. 18 - Determine what is wrong with the name of each...Ch. 18 - Determine what is wrong with the name of each...Ch. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - 56. Name each alkane.
Ch. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - 60. Provide correct structures for each compound.
...Ch. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Prob. 63ECh. 18 - Complete the table.Ch. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Prob. 67ECh. 18 - Prob. 68ECh. 18 - What are the products of this alkene addition...Ch. 18 - Prob. 70ECh. 18 - Prob. 71ECh. 18 - Prob. 72ECh. 18 - Prob. 73ECh. 18 - Prob. 74ECh. 18 - Name each monosubstituted benzene.Ch. 18 - Prob. 76ECh. 18 - Prob. 77ECh. 18 - Prob. 78ECh. 18 - Prob. 79ECh. 18 - Prob. 80ECh. 18 - Prob. 81ECh. 18 - Prob. 82ECh. 18 - Based on its functional group, match the structure...Ch. 18 - Prob. 84ECh. 18 - Prob. 85ECh. 18 - Prob. 86ECh. 18 - Prob. 87ECh. 18 - Prob. 88ECh. 18 - Prob. 89ECh. 18 - Draw a structure for each alcohol. a. 1-hexanol b....Ch. 18 - Prob. 91ECh. 18 - Prob. 92ECh. 18 - Prob. 93ECh. 18 - For each compound, provide a name if the structure...Ch. 18 - Prob. 95ECh. 18 - Prob. 96ECh. 18 - Prob. 97ECh. 18 - Prob. 98ECh. 18 - Prob. 99ECh. 18 - Prob. 100ECh. 18 - Prob. 101ECh. 18 - Prob. 102ECh. 18 - Identify each organic compound as an alkane,...Ch. 18 - Prob. 104ECh. 18 - 105. Name each compound.
Ch. 18 - Name each compound.Ch. 18 - Prob. 107ECh. 18 - Prob. 108ECh. 18 - Prob. 109ECh. 18 - Prob. 110ECh. 18 - Prob. 111ECh. 18 - How many kilograms of CO2 are produced by the...Ch. 18 - Prob. 113ECh. 18 - Prob. 114ECh. 18 - Prob. 115ECh. 18 - Prob. 116ECh. 18 - Using complete sentences, compare and contrast...Ch. 18 - The octane rating for gasoline is a measurement of...Ch. 18 - Prob. 120QGWCh. 18 - Prob. 121DIA
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