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Chemistry [hardcover]
5th Edition
ISBN: 9780393264845
Author: Geoffery Davies
Publisher: NORTON
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Chapter 18, Problem 18.93AP
Interpretation Introduction
Interpretation: The value of equilibrium constant for the given reaction is to be calculated.
Concept introduction: The species that has higher reduction potential it undergoes reduction while the species with lower value of reduction potential in comparison to other species undergoes the oxidation reaction.
To determine: The value of equilibrium constant for the given reaction.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 18 Solutions
Chemistry [hardcover]
Ch. 18.2 - Prob. 1PECh. 18.2 - Prob. 2PECh. 18.3 - Prob. 3PECh. 18.4 - Prob. 4PECh. 18.6 - Prob. 5PECh. 18.6 - Prob. 6PECh. 18.7 - Prob. 7PECh. 18.9 - Prob. 8PECh. 18 - Prob. 18.1VPCh. 18 - Prob. 18.2VP
Ch. 18 - Prob. 18.3VPCh. 18 - Prob. 18.4VPCh. 18 - Prob. 18.5VPCh. 18 - Prob. 18.6VPCh. 18 - Prob. 18.7VPCh. 18 - Prob. 18.8VPCh. 18 - Prob. 18.9VPCh. 18 - Prob. 18.10VPCh. 18 - Prob. 18.11QPCh. 18 - Prob. 18.12QPCh. 18 - Prob. 18.13QPCh. 18 - Prob. 18.14QPCh. 18 - Prob. 18.15QPCh. 18 - Prob. 18.16QPCh. 18 - Prob. 18.17QPCh. 18 - Prob. 18.18QPCh. 18 - Prob. 18.19QPCh. 18 - Prob. 18.20QPCh. 18 - Prob. 18.21QPCh. 18 - Prob. 18.22QPCh. 18 - Prob. 18.23QPCh. 18 - Prob. 18.24QPCh. 18 - Prob. 18.25QPCh. 18 - Prob. 18.26QPCh. 18 - Prob. 18.27QPCh. 18 - Prob. 18.28QPCh. 18 - Prob. 18.29QPCh. 18 - Prob. 18.30QPCh. 18 - Prob. 18.31QPCh. 18 - Prob. 18.32QPCh. 18 - Prob. 18.33QPCh. 18 - Prob. 18.34QPCh. 18 - Prob. 18.35QPCh. 18 - Prob. 18.36QPCh. 18 - Prob. 18.37QPCh. 18 - Prob. 18.38QPCh. 18 - Prob. 18.39QPCh. 18 - Prob. 18.40QPCh. 18 - Prob. 18.41QPCh. 18 - Prob. 18.42QPCh. 18 - Prob. 18.43QPCh. 18 - Prob. 18.44QPCh. 18 - Prob. 18.45QPCh. 18 - Prob. 18.46QPCh. 18 - Prob. 18.47QPCh. 18 - Prob. 18.48QPCh. 18 - Prob. 18.49QPCh. 18 - Prob. 18.50QPCh. 18 - Prob. 18.51QPCh. 18 - Prob. 18.52QPCh. 18 - Prob. 18.53QPCh. 18 - Prob. 18.54QPCh. 18 - Prob. 18.55QPCh. 18 - Prob. 18.56QPCh. 18 - Prob. 18.57QPCh. 18 - Prob. 18.58QPCh. 18 - Prob. 18.59QPCh. 18 - Prob. 18.60QPCh. 18 - Prob. 18.61QPCh. 18 - Prob. 18.62QPCh. 18 - Prob. 18.63QPCh. 18 - Prob. 18.64QPCh. 18 - Prob. 18.65QPCh. 18 - Prob. 18.66QPCh. 18 - Prob. 18.67QPCh. 18 - Prob. 18.68QPCh. 18 - Prob. 18.69QPCh. 18 - Prob. 18.70QPCh. 18 - Prob. 18.71QPCh. 18 - Prob. 18.72QPCh. 18 - Prob. 18.73QPCh. 18 - Prob. 18.74QPCh. 18 - Prob. 18.75QPCh. 18 - Prob. 18.76QPCh. 18 - Prob. 18.77QPCh. 18 - Prob. 18.78QPCh. 18 - Prob. 18.79QPCh. 18 - Prob. 18.80QPCh. 18 - Prob. 18.81QPCh. 18 - Prob. 18.82QPCh. 18 - Prob. 18.83QPCh. 18 - Prob. 18.84QPCh. 18 - Prob. 18.85QPCh. 18 - Prob. 18.86QPCh. 18 - Prob. 18.87QPCh. 18 - Prob. 18.88QPCh. 18 - Prob. 18.89QPCh. 18 - Prob. 18.90QPCh. 18 - Prob. 18.91APCh. 18 - Prob. 18.92APCh. 18 - Prob. 18.93APCh. 18 - Prob. 18.94APCh. 18 - Prob. 18.95APCh. 18 - Prob. 18.96APCh. 18 - Prob. 18.97APCh. 18 - Prob. 18.98APCh. 18 - Prob. 18.99APCh. 18 - Prob. 18.100AP
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