Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
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ISBN: 9780133900811
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 18, Problem 18.64SP
Interpretation Introduction
Interpretation:
To indicate the direction of electron and ion flow of galvanic cell.
Concept introduction:
A galvanic cell comprises of two cells with the end goal that the cathode of one half cells is made out of metal and the anode of the other half cell is made out of metal.
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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major
contributor in each case, or if they are equivalent (45)
(2)
-PH2
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+0
Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
Chapter 18 Solutions
Chemistry, Books a la Carte Plus Mastering Chemistry with eText -- Access Card Package (7th Edition)
Ch. 18 - Prob. 18.1PCh. 18 - Prob. 18.2ACh. 18 - Prob. 18.3PCh. 18 - APPLY 18.4 Balance the following net ionic...Ch. 18 - Prob. 18.5PCh. 18 - Prob. 18.6ACh. 18 - PRACTICE 18.7 Write a balanced equation for the...Ch. 18 - Prob. 18.8ACh. 18 - Prob. 18.9PCh. 18 - Prob. 18.10A
Ch. 18 - Prob. 18.11PCh. 18 - Prob. 18.12PCh. 18 - Prob. 18.13ACh. 18 - Prob. 18.14PCh. 18 - Prob. 18.15ACh. 18 - PRACTICE 18.16 Consider a galvanic cell that uses...Ch. 18 - Prob. 18.17ACh. 18 - Conceptual PRACTICE 18.18 Consider the following...Ch. 18 - Prob. 18.19ACh. 18 - Prob. 18.20PCh. 18 - Prob. 18.21ACh. 18 - Prob. 18.22PCh. 18 - Prob. 18.23ACh. 18 - PROBLEM 18.24 Write a balanced equation for the...Ch. 18 - Prob. 18.25PCh. 18 - Prob. 18.26PCh. 18 - PROBLEM 18.27 Predict the half-cell reactions that...Ch. 18 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Prob. 18.30ACh. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - PROBLEM 18.34 Use the thermodynamic data in...Ch. 18 - Prob. 18.35PCh. 18 - Prob. 18.36PCh. 18 - The following picture of a galvanic cell has lead...Ch. 18 - Prob. 18.38CPCh. 18 - Prob. 18.39CPCh. 18 - Prob. 18.40CPCh. 18 - Prob. 18.41CPCh. 18 - Prob. 18.42CPCh. 18 - 18.43 Consider a Daniell cell with 1.0 M ion...Ch. 18 - Prob. 18.44CPCh. 18 - Prob. 18.45CPCh. 18 - Prob. 18.46SPCh. 18 - Prob. 18.47SPCh. 18 - Prob. 18.48SPCh. 18 - Prob. 18.49SPCh. 18 - Prob. 18.50SPCh. 18 - Prob. 18.51SPCh. 18 - Prob. 18.52SPCh. 18 - Prob. 18.53SPCh. 18 - Prob. 18.54SPCh. 18 - Prob. 18.55SPCh. 18 - Prob. 18.56SPCh. 18 - Prob. 18.57SPCh. 18 - Prob. 18.58SPCh. 18 - Prob. 18.59SPCh. 18 - Prob. 18.60SPCh. 18 - Describe galvanic cells that use the following...Ch. 18 - Prob. 18.62SPCh. 18 - Prob. 18.63SPCh. 18 - Prob. 18.64SPCh. 18 - Prob. 18.65SPCh. 18 - Prob. 18.66SPCh. 18 - Prob. 18.67SPCh. 18 - 18.68 Write balanced equations for the electrode...Ch. 18 - Prob. 18.69SPCh. 18 - Prob. 18.70SPCh. 18 - Prob. 18.71SPCh. 18 - Prob. 18.72SPCh. 18 - Prob. 18.73SPCh. 18 - Prob. 18.74SPCh. 18 - Prob. 18.75SPCh. 18 - Prob. 18.76SPCh. 18 - Prob. 18.77SPCh. 18 - Prob. 18.78SPCh. 18 - Prob. 18.79SPCh. 18 - Prob. 18.80SPCh. 18 - Prob. 18.81SPCh. 18 - Prob. 18.82SPCh. 18 - Prob. 18.83SPCh. 18 - Prob. 18.84SPCh. 18 - Prob. 18.85SPCh. 18 - Prob. 18.86SPCh. 18 - Prob. 18.87SPCh. 18 - Prob. 18.88SPCh. 18 - Prob. 18.89SPCh. 18 - Prob. 18.90SPCh. 18 - Prob. 18.91SPCh. 18 - What reaction can occur, if any, when the...Ch. 18 - Prob. 18.93SPCh. 18 - Prob. 18.94SPCh. 18 - Prob. 18.95SPCh. 18 - Prob. 18.96SPCh. 18 - Prob. 18.97SPCh. 18 - Prob. 18.98SPCh. 18 - Prob. 18.99SPCh. 18 - Prob. 18.100SPCh. 18 - Prob. 18.101SPCh. 18 - Prob. 18.102SPCh. 18 - Prob. 18.103SPCh. 18 - Prob. 18.104SPCh. 18 - Prob. 18.105SPCh. 18 - Prob. 18.106SPCh. 18 - From standard reduction potentials, calculate the...Ch. 18 - Prob. 18.108SPCh. 18 - Prob. 18.109SPCh. 18 - Prob. 18.110SPCh. 18 - Prob. 18.111SPCh. 18 - Prob. 18.112SPCh. 18 - Prob. 18.113SPCh. 18 - Prob. 18.114SPCh. 18 - Prob. 18.115SPCh. 18 - Prob. 18.116SPCh. 18 - Prob. 18.117SPCh. 18 - Prob. 18.118SPCh. 18 - Prob. 18.119SPCh. 18 - Prob. 18.120SPCh. 18 - Prob. 18.121SPCh. 18 - Prob. 18.122SPCh. 18 - Prob. 18.123SPCh. 18 - Prob. 18.124SPCh. 18 - What products should be formed when the following...Ch. 18 - Prob. 18.126SPCh. 18 - Prob. 18.127SPCh. 18 - Prob. 18.128SPCh. 18 - Prob. 18.129SPCh. 18 - Prob. 18.130SPCh. 18 - Prob. 18.131SPCh. 18 - Prob. 18.132SPCh. 18 - Prob. 18.133SPCh. 18 - Prob. 18.134CPCh. 18 - Prob. 18.135CPCh. 18 - Prob. 18.136CPCh. 18 - Prob. 18.137CPCh. 18 - Prob. 18.138CPCh. 18 - Consider the following half-reactions and...Ch. 18 - Prob. 18.140CPCh. 18 - Prob. 18.141CPCh. 18 - Prob. 18.142CPCh. 18 - Prob. 18.143CPCh. 18 - Prob. 18.144CPCh. 18 - Prob. 18.145CPCh. 18 - Prob. 18.146CPCh. 18 - Prob. 18.147CPCh. 18 - Prob. 18.148CPCh. 18 - Prob. 18.149CPCh. 18 - Prob. 18.150CPCh. 18 - At one time on Earth, iron was present mostly as...Ch. 18 - Prob. 18.152CPCh. 18 - The following galvanic cell has apotentialof1.214V...Ch. 18 - Prob. 18.154CPCh. 18 - Prob. 18.155CPCh. 18 - Prob. 18.156MPCh. 18 - Prob. 18.157MPCh. 18 - Prob. 18.158MPCh. 18 - Prob. 18.159MPCh. 18 - Prob. 18.160MPCh. 18 - Prob. 18.161MPCh. 18 - Prob. 18.162MPCh. 18 - Prob. 18.163MPCh. 18 - Prob. 18.164MPCh. 18 - The half-reactions that occur in ordinary alkaline...Ch. 18 - Prob. 18.166MPCh. 18 - Prob. 18.167MP
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