Chapter 18, Problem 18.5QAP

Interpretation Introduction

(a)

Interpretation:

The ratio and comparison of intensities of the anti-Stokes and Stokes line for ${\text{CCl}}_4$ at frequency shift of $218{\text{cm}}^{-1}$.

Concept introduction:

The intensity of stocks lines is directly proportional to the population of higher state and intensity of anti-stocks is directly proportional to the population of lower state. The change in energy of Raman lines is directly proportional to the frequency shift.

Interpretation Introduction

(b)

Interpretation:

The ratio and comparison of intensities of the anti-Stokes and Stokes line for ${\text{CCl}}_4$ at frequency shift of $459{\text{cm}}^{-1}$.

Concept introduction:

The intensity of stocks lines is directly proportional to the population of higher state and intensity of anti-stocks is directly proportional to the population of lower state. The change in energy of Raman lines is directly proportional to the frequency shift.

Interpretation Introduction

(b)

Interpretation:

The ratio and comparison of intensities of the anti-Stokes and Stokes line for ${\text{CCl}}_4$ at frequency shift of $790{\text{cm}}^{-1}$.

Concept introduction:

The intensity of stocks lines is directly proportional to the population of higher state and intensity of anti-stocks is directly proportional to the population of lower state. The change in energy of Raman lines is directly proportional to the frequency shift.