EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Question
Chapter 18, Problem 18.59P
Interpretation Introduction
Interpretation:
The mechanism of treatment of water on isonitrile to form N-alkylformamide is to be proposed.
Concept introduction:
Nitriles can be hydrolyzed to amides under acidic or basic condition. The treatment of nitrile with water under acidic conditions produces a primary amide
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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!
Chapter 18 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. 18 - Prob. 18.1PCh. 18 - Prob. 18.2PCh. 18 - Prob. 18.3PCh. 18 - Prob. 18.4PCh. 18 - Prob. 18.5PCh. 18 - Prob. 18.6PCh. 18 - Prob. 18.7PCh. 18 - Prob. 18.8PCh. 18 - Prob. 18.9PCh. 18 - Prob. 18.10P
Ch. 18 - Prob. 18.11PCh. 18 - Prob. 18.12PCh. 18 - Prob. 18.13PCh. 18 - Prob. 18.14PCh. 18 - Prob. 18.15PCh. 18 - Prob. 18.16PCh. 18 - Prob. 18.17PCh. 18 - Prob. 18.18PCh. 18 - Prob. 18.19PCh. 18 - Prob. 18.20PCh. 18 - Prob. 18.21PCh. 18 - Prob. 18.22PCh. 18 - Prob. 18.23PCh. 18 - Prob. 18.24PCh. 18 - Prob. 18.25PCh. 18 - Prob. 18.26PCh. 18 - Prob. 18.27PCh. 18 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Prob. 18.30PCh. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Prob. 18.36PCh. 18 - Prob. 18.37PCh. 18 - Prob. 18.38PCh. 18 - Prob. 18.39PCh. 18 - Prob. 18.40PCh. 18 - Prob. 18.41PCh. 18 - Prob. 18.42PCh. 18 - Prob. 18.43PCh. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - Prob. 18.46PCh. 18 - Prob. 18.47PCh. 18 - Prob. 18.48PCh. 18 - Prob. 18.49PCh. 18 - Prob. 18.50PCh. 18 - Prob. 18.51PCh. 18 - Prob. 18.52PCh. 18 - Prob. 18.53PCh. 18 - Prob. 18.54PCh. 18 - Prob. 18.55PCh. 18 - Prob. 18.56PCh. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Prob. 18.59PCh. 18 - Prob. 18.60PCh. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - Prob. 18.63PCh. 18 - Prob. 18.64PCh. 18 - Prob. 18.65PCh. 18 - Prob. 18.66PCh. 18 - Prob. 18.67PCh. 18 - Prob. 18.68PCh. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - Prob. 18.71PCh. 18 - Prob. 18.72PCh. 18 - Prob. 18.73PCh. 18 - Prob. 18.74PCh. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - Prob. 18.77PCh. 18 - Prob. 18.78PCh. 18 - Prob. 18.79PCh. 18 - Prob. 18.80PCh. 18 - Prob. 18.81PCh. 18 - Prob. 18.82PCh. 18 - Prob. 18.83PCh. 18 - Prob. 18.84PCh. 18 - Prob. 18.85PCh. 18 - Prob. 18.86PCh. 18 - Prob. 18.87PCh. 18 - Prob. 18.88PCh. 18 - Prob. 18.89PCh. 18 - Prob. 18.90PCh. 18 - Prob. 18.91PCh. 18 - Prob. 18.92PCh. 18 - Prob. 18.93PCh. 18 - Prob. 18.94PCh. 18 - Prob. 18.95PCh. 18 - Prob. 18.96PCh. 18 - Prob. 18.97PCh. 18 - Prob. 18.98PCh. 18 - Prob. 18.99PCh. 18 - Prob. 18.100PCh. 18 - Prob. 18.101PCh. 18 - Prob. 18.102PCh. 18 - Prob. 18.103PCh. 18 - Prob. 18.1YTCh. 18 - Prob. 18.2YTCh. 18 - Prob. 18.3YTCh. 18 - Prob. 18.4YTCh. 18 - Prob. 18.5YTCh. 18 - Prob. 18.6YTCh. 18 - Prob. 18.7YTCh. 18 - Prob. 18.8YTCh. 18 - Prob. 18.9YTCh. 18 - Prob. 18.10YTCh. 18 - Prob. 18.11YTCh. 18 - Prob. 18.12YTCh. 18 - Prob. 18.13YTCh. 18 - Prob. 18.14YTCh. 18 - Prob. 18.15YT
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