OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
8th Edition
ISBN: 9781305865617
Author: Brown, Iverson, Anslyn, FOOTE
Publisher: Cengage Learning US
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Chapter 18, Problem 18.54P
Interpretation Introduction

Interpretation:

The way by which the given synthesis is being accomplished has to be shown and explanation for the stereoselective synthesis of 10-trans-12-cis isomer.

Concept introduction:

Wittig Reaction: It is an organic reaction where an aldehyde or a ketone gets converted to an alkene by replacing carbonyl group by a C=C bond. A phosphorous ylide is used for this conversion. It is a neutral molecule where a positively charged phosphorous is attached to a negatively charged carbon atom.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 18, Problem 18.54P

Non-stabilized ylide (having electron donating group on negatively charged carbon) gives Z-isomer whereas stabilized ylide (having electron withdrawing group on negatively charged carbon) gives E-isomer.

Non–stabilized ylide (having electron donating group on negatively charged carbon) gives Z–isomer whereas stabilized ylide (having electron withdrawing group on negatively charged carbon) gives E–isomer.

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Chapter 18 Solutions

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition

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