(a) Interpretation: Standard free energy change for the pyruvate kinase reaction should be calculated. Concept Introduction: In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate. The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

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Answer 1

Question

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

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Fura-2 Fluorescence (Arbitrary Unit) 4500 4000 3500 3000 2500 2000 1500 1000 500 [Ca2+]=2970nM, 25°C [Ca2+] 2970nM, 4°C [Ca2+]=0.9nM, 25°C [Ca2+] = 0.9nM, 4°C 0 260 280 300 340 360 380 400 420 440 Wavelength (nm) ← < The figure on the LHS shows the excitation spectra of Fura-2 (Em = 510 nm) in 2 solutions with two different Ca2+ ion concentration as indicated. Except for temperature, the setting for excitation & signal acquisition was identical.< ப a) The unit in Y-axis is arbitrary (unspecified). Why? < < b) Compare & contrast the excitation wavelength of the Isosbestic Point of Fura-2 at 25 °C & 4 °C. Give a possible reason for the discrepancy. < c) The fluorescence intensity at 25 °C & 4 °C are different. Explain why with the concept of electronic configuration. <

Answer 2

Question

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

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Answer 3

Question

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

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Answer 4

Question

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

Expert Solution & Answer

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Answer 5

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

Answer 6

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Answer 7

Chapter 18, Problem 13P

Interpretation Introduction

(a)

Interpretation:

Standard free energy change for the pyruvate kinase reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

The energy which is used to do work at given pressure and at given temperature especially at 1 bar and 298K respectively is called standard free energy change.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Answer 9

Interpretation Introduction

(b)

Interpretation:

Equilibrium constant for the given reaction should be calculated.

Concept Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

When the reactants and products don’t have any change in the particular time, then it is called equilibrium constant. It is denoted as K

Answer 10

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 18 - Characterizing Glycolysis List the reactions of...Ch. 18 - Radiotracer Labeling of Pyruvate from Glucose...Ch. 18 - Effects of Changing Metabolite Concentrations on...Ch. 18 - Prob. 4P Ch. 18 - Prob. 5P Ch. 18 - The Reactions and Meehanisms of the Leloir Pathway...Ch. 18 - The Effect of lodoacetic Acid on the...Ch. 18 - Prob. 8P Ch. 18 - Comparing Glycolysis Entry Points for Sucrose...Ch. 18 - Prob. 10P

Solution Summary: The author explains that the standard free energy change for the pyruvate kinase reaction should be calculated.

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

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Chapter 18 Solutions

Solution Summary: The author explains that the standard free energy change for the pyruvate kinase reaction should be calculated.

(c) Interpretation: Ratio of [pyruvate][PEP] should be calculated. Introduction: In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.

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Chapter 18 Solutions

(c)

Interpretation:

Ratio of [pyruvate][PEP] should be calculated.

Introduction:

In a cell, ATP is one of the major energies. By decarboxylating of the oxaloacetate and hydrolyzing the guanosine triphosphate, PEP is formed. PEP is abbreviated as Phosphoenolpyruvate.