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Aniline, C6H5NH2, is an important organic base used in the manufacture of dyes. It has
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- What is the pH of a solution that consists of 0.20 M ammonia, NH3, and 0.20 M ammonium chloride, NH4Cl?arrow_forwardFor conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)arrow_forwardMalic acid is a weak diprotic organic acid with Ka1 = 4.0 104 and Ka2 = 9.0 105. a Letting the symbol H2A represent malic acid, write the chemical equations that represent Ka1 and Ka2. Write the chemical equation that represents Ka1 Ka2. b Qualitatively describe the relative concentrations of H2A, HA, A2, and H3O+ in a solution that is about one molar in malic acid. c Calculate the pH of a 0.0175 M malic acid solution and the equilibrium concentration of [H2A]. d What is the A2 concentrationin in solutions b and c?arrow_forward
- What is the pH of a solution prepared by mixing 55.00 mL of 0.10 M methylamine, CH3NH2, with 15.00 mL of 0.10 M methylammonium chloride, CH3NH3CI? Assume that the volume of the solutions are additive and that Kp = 4.4 x 104 for methylamine.arrow_forwardAt 50°C and 1 atm, K(w)=5.19X10⁻¹⁴. At these conditions,find (a) [H₃O⁺] in pure water, (b) [H₃O⁺] in 0.010 M NaOH,and (c) [OH] in 0.0010 M HClO₄. (d) Find [H₃O⁺] in 0.0100 M KOH at 100°C and 1000 atm (K(w)=1.10X10⁻¹²). (e) Find the pH of pure water at 100°C and 1000 atm.arrow_forward4. The value of K, for acetylsalicylic acid (aspirin), HC,H,O4, is 3.00×104 . Write the equation for the reaction that goes with this equilibrium constant. (Use H3O+ instead of Ht.)arrow_forward
- Using Le chateleir principle, predict how the concentration of each substance changes by the addition of OH^-arrow_forward15.0 mL of 0.50 M HCl is added to a 100.-mL sample of 0.314 M HNO 2 ( K a for HNO 2 = 4.0 × 10 –4). What is the equilibrium concentration of NO 2 – ions?arrow_forwardACID-BASE EQUILIBRIA Doc Jill wants to determine the Ao of a weak acid she isolated called Yurdaughteric acid (HYd). She prepared a solution of the weak acid by diluting 3.5 ml of 0.10 M HYd with 13.5 mL of water. Upon measuring the conductivity of the solution and a blank, she obtained 192.0 uS/cm and 4.0 uS/cm, respectively. She also measured the pH of the solution and got a pH of 3.12. Help her find the following: 1. Concentration of the weak acid (HYd) after dilution 2. Corrected conductivity 3. Molar conductivity of the solution 4. Equilibrium concentration of H30and Ydarrow_forward
- ACID-BASE EQUILIBRIA Doc Jill wants to determine the Ao of a weak acid she isolated called Yurdaughteric acid (HYd). She prepared a solution of the weak acid by diluting 3.5 mL of 0.10 M HYd with 13.5 mL of water. Upon measuring the conductivity of the solution and a blank, she obtained 192.0 uS/cm and 4.0 uS/cm, respectively. She also measured the pH of the solution and got a pH of 3.12. Help her find the following: 5. a 6. Equilibrium concentration of the weak acid (HYd) 7. K, 8. Aoarrow_forwardC6H4NH2COOH, para-aminobenzoic acid (PABA), is used in some sunscreen agents. Calculate the concentrations of hydronium ion and para-aminobenzoate ion, C,H,NH2COO, in a 8.0 x 10-2 M solution of the acid. The value of Ka is 2.2 x 10-5. Concentration of hydronium ion = | м Concentration of para-aminobenzoate ion =|| |мarrow_forwardThe values of K a for hydrozoic acid ( HN 3) and hypobromous acid (HB1O) are given below. HN3 Ką = 1.9 x 10-5 HBrO Ka = 2.0 x 10-9 If we mix 0.50 mol HN 3 and 0.50 mol NaBrO into a 1-L aqueous solution, which of the following statements is correct concerning the final solution at cquilibrium after mixing? O a. The pH of the final solution is greater than 7 because Ką (HN3) K½(BrO"). O . The pH of the final solution is equal to 7 because the neutralization reaction between HN3 and NaBro. d. The pH of the final solution is less than 7 because Ką (HN3) > Kh( BrO" ). O e. The pH of the final solution is less than 7 because Ką (HN3) < K,( BrO" ).arrow_forward
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