For the given Diels-Alder reaction, the product formed should be determined. Concept introduction: Cycloaddition reaction is a concerted addition reaction of two reactants to form a ring; in which two π-bonds are converted to two σ-bonds . Diels-Alder reaction is a [ 4+2 ] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene . The mechanism of the ring formation in the Diels-Alder reaction is drawn by using three arrows representing the shifting of π-bonds in the two π-systems in a clockwise or counter clockwise fashion, so that the ring formation will take place. If the dienophile is a trans- alkene , then the product will be trans-product. To determine: the product formed for the given Diels-Alder reaction.

Question

5. Propose a Synthesis for the molecule below. You may use any starting materials containing 6 carbons or less (reagents that aren't incorporated into the final molecule such as PhзP do not count towards this total, and the starting material can have whatever non-carbon functional groups you want), and any of the reactions you have learned so far in organic chemistry I, II, and III. Your final answer should show each step separately, with intermediates and conditions clearly drawn. H3C CH3

Answer 1

Question

Chapter 17.7, Problem 3LTS

Interpretation Introduction

Interpretation:

For the given Diels-Alder reaction, the product formed should be determined.

Concept introduction:

Cycloaddition reaction is a concerted addition reaction of two reactants to form a ring; in which two π-bonds are converted to two σ-bonds.

Diels-Alder reaction is a [4+2] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene.

The mechanism of the ring formation in the Diels-Alder reaction is drawn by using three arrows representing the shifting of π-bonds in the two π-systems in a clockwise or counter clockwise fashion, so that the ring formation will take place.

If the dienophile is a trans-alkene, then the product will be trans-product.

To determine: the product formed for the given Diels-Alder reaction.

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