a) 2-Methyl-2-propanol Interpretation: A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given. Concept introduction: Grignard reagents react with formaldehyde to produce 1 0 alcohols, with other aldehydes to yield 2 0 alcohols and with ketones to give 3 0 alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3 0 alcohols. To give: A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Question

The number of microstates corresponding to each macrostate is given by N. The dominant macrostate or configuration of a system is the macrostate with the greatest weight W. Are both statements correct?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

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The number of microstates corresponding to each macrostate is given by N. The dominant macrostate or configuration of a system is the macrostate with the greatest weight W. Are both statements correct?

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

Expert Solution & Answer

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Answer 5

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

Answer 6

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Answer 7

Chapter 17.5, Problem 10P

Interpretation Introduction

a) 2-Methyl-2-propanol

Interpretation:

A method to prepare 2-methyl-2-propanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 2-methyl-2-propanol using a Grignard reagent.

Answer 8

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Answer 9

Interpretation Introduction

b) 1-Methylcyclohexanol

Interpretation:

A method to prepare 1-methylcyclohexanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 1-methylcyclohexanol using a Grignard reagent.

Answer 10

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Answer 11

Interpretation Introduction

c) 3-Methyl-3-pentanol

Interpretation:

A method to prepare 3-methyl-3 pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 3-methyl-3-pentanol using a Grignard reagent.

Answer 12

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Answer 13

Interpretation Introduction

d) 2-Phenyl-2-butanol

Interpretation:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product

To give:

A method to prepare 2-phenyl-2-butanol using a Grignard reagent.

Answer 14

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Answer 15

Interpretation Introduction

e) Benzyl alcohol

Interpretation:

A method to prepare benzyl alcohol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare benzyl alcohol using a Grignard reagent.

Answer 16

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

Answer 17

Interpretation Introduction

f) 4-Methyl-1-pentanol

Interpretation:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent is to be given.

Concept introduction:

Grignard reagents react with formaldehyde to produce 1⁰ alcohols, with other aldehydes to yield 2⁰ alcohols and with ketones to give 3⁰ alcohols as the product. Esters also when treated with two molar equivalents of Grignard reagents yield 3⁰ alcohols.

To give:

A method to prepare 4-methyl-1-pentanol using a Grignard reagent.

Answer 18

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Answer 29

Ch. 17.1 - Give IUPAC names for the following compounds:Ch. 17.1 - Prob. 2P Ch. 17.2 - The following data for isomeric four-carbon...Ch. 17.2 - Rank the following substances in order of...Ch. 17.2 - Prob. 5P Ch. 17.3 - Prob. 6P Ch. 17.4 - What reagent would you use to accomplish each of...Ch. 17.4 - Prob. 8P Ch. 17.5 - Prob. 9P Ch. 17.5 - Prob. 10P

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Chapter 17 Solutions