EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 17.5, Problem 10CC
Interpretation Introduction

Interpretation For the given compounds, it should be checked whether the compound will be aromatic, nonaromatic or anti aromatic

Concept introduction:

  • The conditions for aromatic compound are,
    1. 1. It should be planar
    2. 2. It must obey the Huckel’s rule

The requirement of an odd number of electron pair is called Huckel’s rule. A     compound can only be aromatic if the number of π electron in the ring is 2, 6,10,14,18 and so on. This series of number can be expressed mathematically as 4n+2 , where n should be an integer and the compound is aromatic.

  1. 3. Continuous conjugated π system(all carbon should be in sp2 hybridized state)
  • The conditions for non-aromatic compound is

The compound not either planar or cyclic but it must satisfy the Huckel’s                         rule

  • The conditions for anti-aromatic compound is

    It satisfy all the conditions except Huckel’s rule in the conditions of aromaticity

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