EBK ORGANIC CHEMISTRY-PRINT COMPANION (
EBK ORGANIC CHEMISTRY-PRINT COMPANION (
4th Edition
ISBN: 9781119776741
Author: Klein
Publisher: WILEY CONS
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Chapter 17, Problem 66IP
Interpretation Introduction

Interpretation For the given compounds, the function of lone pair of electrons on the nitrogen atom should be explained

Concept introduction:

  • The conditions for aromatic compound are,
    1. 1. It should be planar
    2. 2. It must obey the Huckel’s rule

The requirement of an odd number of electron pair is called Huckel’s rule. A compound can only be aromatic if the number of π electron in the ring is 2, 6,10,14,18 and so on. This series of number can be expressed mathematically as 4n+2 , where n should be an integer and the compound is aromatic.

  1. 3. Continuous conjugated π system(all carbon should be in sp2 hybridized state)

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Hello! I have a 500 Hz H-NMR for 1,5-bis-(4-methoxyphenyl)-penta-1,4-dien-3-one. I need to label the signals with the corresponding H's. Then, find out if the two alkenes are cis or trans by calculating the J values.  I believe that I have the H-NMR labeled correctly, but not sure if I got the J values correct to determine if the two alkenes in the compound will make the compound cis or trans.
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