An example for each of the given compounds has to be stated: A β -keto nitrile Concept introduction: In a β -keto nitrile , the keto group is placed at the β position of the cyanide group. In a β -diester , one ester group is at a β position to the second ester group. In a β -keto aldehyde , the keto group is placed at the β position to the aldehyde group.

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Answer 1

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Give an example for each of the following:a. a b-keto nitrile b. a b-diester c. a b-keto aldehyde

An aldehyde can be oxidized to produce a carboxylic acid.Draw the carboxylic acid that would be produced by theoxidation of each of the following aldehydes:a. 3-Methylpentanal c. 2,4-Diethylhexanalb. 2,3-Dichlorobutanal d. 2-Methylpropanal

Please answer: TEST FOR ALDEHYDES AND KETONES 1. Fehlings Test a. General Reaction b. Reagents c. Positive result 2. Schiff’s Test a. General Reaction b. Reagents c. Positive result TEST FOR CARBOXYLIC ACIDS 1. Acidity a. General Reaction b. Reagents c. Positive result 2. Esterification with Alcohol a. General Reaction b. Reagents c. Positive result

Answer 2

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Answer 3

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Answer 4

Question

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

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Answer 5

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 6

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 7

Chapter 17.1, Problem 2P

(a)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

A β-keto nitrile

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 8

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 9

(b)

Interpretation Introduction

Interpretation: An example for each of the given compounds has to be stated:

a β-diester

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 10

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 11

(c)

Interpretation Introduction

Interpretation: An example for each of the following compounds has to be stated:

a β-keto aldehyde

Concept introduction: In a β-keto nitrile, the keto group is placed at the β position of the cyanide group.

In a β-diester, one ester group is at a β position to the second ester group.

In a β-keto aldehyde, the keto group is placed at the β position to the aldehyde group.

Answer 12

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Answer 14

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Answer 15

Ch. 17.1 - Prob. 1P Ch. 17.1 - Prob. 2P Ch. 17.1 - Prob. 3P Ch. 17.1 - Prob. 4P Ch. 17.1 - Rank the compounds in each of the following groups...Ch. 17.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 17.3 - Draw the enol tautomers for each of the following...Ch. 17.3 - Prob. 8P Ch. 17.4 - Prob. 9P Ch. 17.4 - Prob. 10P

Solution Summary: The author illustrates how the positions of carbon atoms in the compound can be visualized as given below.

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Chapter 17 Solutions