The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered. Concept introduction: The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation. The value of E cell is calculated using Nernst formula, E = E ° − ( R T n F ) ln ( Q ) At room temperature the above equation is specifies as, E = E ° − ( 0.0591 n ) log ( Q ) This relation is further used to determine the relation between Δ G ° and K , Δ G ° and E ° cell . To determine: The overall cell reaction and E ° cell for the given cell reaction.

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Answer 1

Question

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

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Answer 2

Question

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

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Answer 3

Question

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

Expert Solution & Answer

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Answer 4

Question

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

Expert Solution & Answer

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See solution

Answer 5

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

Answer 6

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

Answer 7

Chapter 17, Problem 78E

(a)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The overall cell reaction and E°cell for the given cell reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

Answer 9

(b)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of ΔG° and K for the cell reaction at 25 °C .

Answer 10

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

Answer 11

(c)

Interpretation Introduction

Interpretation:

The half-reaction taking place in a galvanic cell is given. Various questions based on the cell reaction are to be answered.

Concept introduction:

The relationship between reduction potential and standard reduction potential value and activities of species present in an electrochemical cell at a given temperature is given by the Nernst equation.

The value of Ecell is calculated using Nernst formula,

E=E°−(RTnF)ln(Q)

At room temperature the above equation is specifies as,

E=E°−(0.0591n)log(Q)

This relation is further used to determine the relation between ΔG° and K , ΔG° and E°cell .

To determine: The value of Ecell for the given concentrations of Au3+ and Tl+ .

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 17 - What is a half-reaction? Why must the number of...Ch. 17 - Galvanic cells harness spontaneous...Ch. 17 - Table 17-1 lists common half-reactions along with...Ch. 17 - Prob. 4RQ Ch. 17 - The Nernst equation allows determination of the...Ch. 17 - Prob. 6RQ Ch. 17 - Prob. 7RQ Ch. 17 - Prob. 8RQ Ch. 17 - What characterizes an electrolytic cell? What is...Ch. 17 - Sketch a galvanic cell, and explain how it works....

Solution Summary: The author explains the oxidation half-reaction taking place in a galvanic cell. The value of E°_cell is calculated using the Nernst equation.

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