PRINCIPLES OF MODERN CHEMISTRY-OWLV2
8th Edition
ISBN: 9781305271609
Author: OXTOBY
Publisher: CENGAGE L
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Chapter 17, Problem 70P
the electroplating of a silver spoon, the spoon acts as thecathode and a piece of pure silver as the anode. Both dipinto a solution of silver cyanide (AgCN). Suppose that acurrent of 1.5 A is passed through such a cell for 22 minutesand that the spoon has a surface area of
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9.26 Explain in detail how you would distinguish between the following sets of compounds using the indicated method
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1H NMR
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9.21 How many 13C NMR signals would you predict for each of the compounds shown in Problem 9.20?
OH
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OH
Chapter 17 Solutions
PRINCIPLES OF MODERN CHEMISTRY-OWLV2
Ch. 17 - Diagram the following galvanic cell, indicating...Ch. 17 - A galvanic cell is constructed in which a Br2Br+...Ch. 17 - A galvanic cell is constructed in which the...Ch. 17 - Prob. 67PCh. 17 - Galvanized steel consists of steel with a thin...Ch. 17 - the electroplating of a silver spoon, the spoon...Ch. 17 - In some old European churches, the stained-glass...Ch. 17 - Consider a galvanic cell for which the anode...
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- Which of the following would be the expected major product and why? HCI CI II CI Product I because of resonance stabilization of the carbocation intermediate Product II because of resonance stabilization of the carbocation intermediate Product I because of inductive stabilization of the carbocation intermediate Product II because of inductive stabilization of the carbocation intermediatearrow_forwardNonearrow_forward9.20 How many ¹H NMR signals (not peaks) would you predict for each of the following compounds? (Consider all protons that would be chemical shift nonequivalent.) OH Br OHarrow_forward
- 9.22 Propose a structure for an alcohol with molecular formula C5H12O that has the 1H NMR spectrum given in Figurearrow_forwardFor each set of carbonyl additions, circle the carbonyl addition that occurs at the faster rate (assuming everything is the same except that the reagent/substrate differs - i.e., same temperature, and ratios/concentrations of reagent and substrate). Electrostatic attraction has a greater impact on the relative rates than steric hindrance. (a) CH3OH HO OCH3 H H CH3 i CH₂OH HO OCH 3 H F3C CH3 (b) F3C NaOCH3 HO OCH3 H3C CH3 H3C CH3 CH3OH HO OCH3 H3C CH3 H3C CH3 (c) NaSCH3 OSCH 3 H3C CH3 H3C CH3 NaOCH3 O OCH 3 H3C CH3 H3C CH3arrow_forward9.34. Assign the chemical shifts and splitting patterns to specific aspects of the structure you propose. C5H12O 1H 2H 2 6H ille H(ppm) 1 3H и 0arrow_forward
- HO (c) (1 pt) Both of the following are hydride donors. Circle the harder nucleophile of -P-Cu-H Н H-AI-H HINIH Н (d) (4 pts) The following reaction involves two steps. Draw the anionic intermediate that forms after sodium hydride reacts and the final organic product. Hints: what type of nucleophile is NaH and where does that mean it will react? Also, the second step is not a proton transfer. What's the most likely reaction for that intermediate to undergo? NaH anionic intermediate final productarrow_forwardPredict the product(s) for the reaction shown. O excess HBr heatarrow_forwardPlease help graph these plotts belowarrow_forward
- Please graph the image below:arrow_forward7. Our textbook says that the fragmentation that occurs in the mass spectrometry of alkanes can be understood by realizing that "the differences in energy among ... tertiary, secondary, primary and methyl carbocations in the gas phase are much greater than the differences among comparable radicals. Therefore, where alternative modes of fragmentation are possible, the more stable carbocation tends to form in preference to the more stable radical." Given this information, which one of the following hexane isomers (all C6H14) is most likely to have a strong M-15 peak (that is, a peak at m/z 71)? HINT: You're looking for a compound that forms a 3° carbocation after loss of an electron and a CH³· radical. A) n-hexane D) 2-methylpentane B) 2,2-dimethylbutane E) 3-methylpentane C) 2,3-dimethylbutanearrow_forwardPlease help graph these plots below:arrow_forward
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