Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 17, Problem 70P
the electroplating of a silver spoon, the spoon acts as thecathode and a piece of pure silver as the anode. Both dipinto a solution of silver cyanide (AgCN). Suppose that acurrent of 1.5 A is passed through such a cell for 22 minutesand that the spoon has a surface area of
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
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Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 17 Solutions
Principles of Modern Chemistry
Ch. 17 - Diagram the following galvanic cell, indicating...Ch. 17 - A galvanic cell is constructed in which a Br2Br+...Ch. 17 - A galvanic cell is constructed in which the...Ch. 17 - Prob. 67PCh. 17 - Galvanized steel consists of steel with a thin...Ch. 17 - the electroplating of a silver spoon, the spoon...Ch. 17 - In some old European churches, the stained-glass...Ch. 17 - Consider a galvanic cell for which the anode...
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- A DEPT NMR spectrum is shown for a molecule with the molecular formula of C5H12O. Draw the structure that best fits this data. 200 180 160 140 120 100 一盆 00 40 8- 20 ppm 0 Qarrow_forwardDon't used hand raitingarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H. H. +N=C H H H Cl: Click and drag to start drawing a structure. : ? g B S olo Ar B Karrow_forward
- Don't used hand raitingarrow_forwardS Shown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H H = HIN: H C. :0 H /\ H H Click and drag to start drawing a structure. ×arrow_forwardPlease help me figure out these calculation and what should be plotted. These are notes for my chemistry class.arrow_forward
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