Consider a voltaic cell in which the following reaction takes place. 2F 2+ ( a q ) + H 2 O 2 ( a q ) + 2 H + ( a q ) → 2 Fe 3 + ( a q ) + 2 H 2 O (a) Calculate E °. (b) Write the Nernst equation for the cell. (c) Calculate E at 25°C under the following conditions: [ Fe 2 + ] = 0.00813 M , [ H 2 O 2 ] = 0.914 M , [ Fe 3+ ] = 0.199 M , ph = 2.88 .
Consider a voltaic cell in which the following reaction takes place. 2F 2+ ( a q ) + H 2 O 2 ( a q ) + 2 H + ( a q ) → 2 Fe 3 + ( a q ) + 2 H 2 O (a) Calculate E °. (b) Write the Nernst equation for the cell. (c) Calculate E at 25°C under the following conditions: [ Fe 2 + ] = 0.00813 M , [ H 2 O 2 ] = 0.914 M , [ Fe 3+ ] = 0.199 M , ph = 2.88 .
Solution Summary: The author explains that the value of E o for the given voltaic cell needs to be determined.
Consider a voltaic cell in which the following reaction takes place.
2F
2+
(
a
q
)
+
H
2
O
2
(
a
q
)
+
2
H
+
(
a
q
)
→
2
Fe
3
+
(
a
q
)
+
2
H
2
O
(a) Calculate E°. (b) Write the Nernst equation for the cell. (c) Calculate E at 25°C under the following conditions:
[
Fe
2
+
]
=
0.00813
M
,
[
H
2
O
2
]
=
0.914
M
,
[
Fe
3+
]
=
0.199
M
,
ph
=
2.88
.
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell