EBK ORGANIC CHEMISTRY AS A SECOND LANGU
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
3rd Edition
ISBN: 9781118203774
Author: Klein
Publisher: YUZU
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Chapter 17, Problem 63IP
Interpretation Introduction

Interpretation: Hybridization state in the nitrogen atom whether changes during isomerization has to be determined.

Concept Introduction:

Huckel’s rule states that based on the number of pi electrons planar, monocyclic, and conjugated polyene compounds can be classified as aromatic or anti-aromatic.

  1. a) The number of π electrons in a cyclic conjugated system is 4n where n is an integer, then it is antiaromatic.
  2. b) The number of π electrons in a cyclic conjugated system is (4n+2) where n is an integer, then it is aromatic.

Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer
curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps

Chapter 17 Solutions

EBK ORGANIC CHEMISTRY AS A SECOND LANGU

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