Introduction To Chemistry
5th Edition
ISBN: 9781259911149
Author: BAUER, Richard C., Birk, James P., Marks, Pamela
Publisher: Mcgraw-hill Education,
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Chapter 17, Problem 53QP
Interpretation Introduction
Interpretation:
The sequence of bases in the complementary strand of DNA molecule that would make hydrogen bond to the base sequence in the given DNA strand is to be identified.
Concept Introduction:
Deoxyribonucleic acid, DNA, is a major genetic material in human beings. Four nitrogen bases found in DNA are adenine, guanine, cytosine, and thymine.
DNA has a double helical structure with two complementary strands. The sequence of nitrogen bases on one strand will be complementary to that on another strand.
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Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
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Introduction To Chemistry
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