ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Question
Chapter 17, Problem 49P
Interpretation Introduction
Interpretation:
The starting materials that lead to the formation of the given products are to be deduced.
Concept introduction:
The starting material used in a reaction can be predicted by retrosynthetic analysis.
Retrosynthetic analysis is the reverse process of
This is achieved by transforming a target molecule into simpler precursor structures without assumptions regarding starting materials. Each precursor material is examined using the same method. This procedure is repeated until simple or commercially available structures are reached.
E.J. Corey formalized this concept in his book The Logic of Chemical Synthesis.
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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not
themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting
four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation
you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be
both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the
four structures.
Compound C
Possible conformations (circle one):
Дет
Lab Data
The distance entered is out of the expected range.
Check your calculations and conversion factors.
Verify your distance. Will the gas cloud be closer to the cotton ball with HCI or NH3?
Did you report your data to the correct number of significant figures?
- X
Experimental Set-up
HCI-NH3
NH3-HCI
Longer Tube
Time elapsed (min)
5 (exact)
5 (exact)
Distance between cotton balls (cm)
24.30
24.40
Distance to cloud (cm)
9.70
14.16
Distance traveled by HCI (cm)
9.70
9.80
Distance traveled by NH3 (cm)
14.60
14.50
Diffusion rate of HCI (cm/hr)
116
118
Diffusion rate of NH3 (cm/hr)
175.2
175.2
How to measure distance and calculate rate
For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically:
1:1 (one mole of EDTA per mole of metal ion)
2:1 (two moles of EDTA per mole of metal ion)
1:2 (one mole of EDTA per two moles of metal ion)
None of the above
Chapter 17 Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
Ch. 17 - Practice Problem 17.1 Give an IUPAC systematic...Ch. 17 - Prob. 2PPCh. 17 - Practice Problem 17.3 Write structural formulas...Ch. 17 - Practice Problem 17.4
Show how each of the...Ch. 17 - Practice Problem 17.5
Show how you could prepare...Ch. 17 - Practice Problem 17.6
(a) Which of the carboxylic...Ch. 17 - Prob. 7PPCh. 17 - Prob. 8PPCh. 17 - Practice Problem 17.9
Esters can also be...Ch. 17 - Prob. 10PP
Ch. 17 - Prob. 11PPCh. 17 - Practice Problem 17.12
What products would you...Ch. 17 - Practice Problem 17.13 (a) Provide the reagents...Ch. 17 - Prob. 14PPCh. 17 - Practice Problem 17.15 Using decarboxylation...Ch. 17 - Practice Problem 17.16 Diacyl peroxides, ,...Ch. 17 - Prob. 17PCh. 17 - Give an IUPAC systematic or common name for each...Ch. 17 - Prob. 19PCh. 17 - Prob. 20PCh. 17 - 17.21 What major organic product would you expect...Ch. 17 - Prob. 22PCh. 17 - Prob. 23PCh. 17 - Prob. 24PCh. 17 - Prob. 25PCh. 17 - 17.26 What products would you expect to obtain...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - 17.28 Indicate reagents that would accomplish each...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - Prob. 30PCh. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - 17.33 On heating,...Ch. 17 - Prob. 34PCh. 17 - Prob. 35PCh. 17 - 17.36 Show how pentanoic acid can be prepared from...Ch. 17 - 17.37 The active ingredient of the insect...Ch. 17 - Prob. 38PCh. 17 - Prob. 39PCh. 17 - Give stereochemical formulas for compounds AQ:...Ch. 17 - 17.41 -Glyceraldehyde can be transformed into...Ch. 17 - Prob. 42PCh. 17 - Prob. 43PCh. 17 - 17.44 Given here are the NMR spectra and carbonyl...Ch. 17 - 17.45 Compound Y dissolves slowly when warmed...Ch. 17 - Prob. 46PCh. 17 - Prob. 47PCh. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - Prob. 51PCh. 17 - 17.52 Starting with 1-naphthol, suggest an...Ch. 17 - Suggest a synthesis of ibuprofen (Section 5.11)...Ch. 17 - Prob. 54PCh. 17 - Prob. 55PCh. 17 - Prob. 1LGPCh. 17 - Prob. 2LGPCh. 17 - Prob. 3LGPCh. 17 - Prob. 4LGP
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