ORGANIC CHEMISTRY 3E WPNGC LL SET 1S 
ORGANIC CHEMISTRY 3E WPNGC LL SET 1S 
3rd Edition
ISBN: 9781119815792
Author: Klein
Publisher: WILEY
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Chapter 17, Problem 47PP
Interpretation Introduction

Interpretation For the given compounds their conjugate base should be explained and it should be checked they are aromatic or not

Concept introduction:

  • Conjugate base is formed by the deprotonation of the parent acid
  • The conditions for aromatic compound are,
    1. 1. It should be planar
    2. 2. It must obey the Huckel’s rule

The requirement of an odd number of electron pair is called Huckel’s rule. A     compound can only be aromatic if the number of π electron in the ring is 2, 6,10,14,18 and so on. This series of number can be expressed mathematically as 4n+2 , where n should be an integer and the compound is aromatic.

  1. 3. Continuous conjugated π system(all carbon should be in sp2 hybridized state)
  • A five membered ring will be aromatic if it contains six π electrons. In order to have six π electrons, one of the carbon atoms must possess two electrons. It should be a carbanion

If any compound which doesn’t satisfy one of the above condition then the compound is not aromatic

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Chapter 17 Solutions

ORGANIC CHEMISTRY 3E WPNGC LL SET 1S 

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