Chapter 17, Problem 2SEPP

Aqueous acid reacts with carbonate Jons to produce carbonic acid, which produces carbon dioxide. A 1.0-L saturated silver carbonate solution at $\text{5°C}$ is treated with enough hydrochloric acid to consume all the carbonate in solution. The carbon dioxide generated is collected in a 19-mL vial and exerts a pressure of 114 mmHg at $\text{25°C}$.

What is the $K_{sp}$ of silver carbonate at $\text{5°C}$ ?

$\begin{array}{l}\text{a)}\hfill \\ \text{2}\text{.5 }\times {\text{ 10}}^{\text{-11}}\hfill \\ \text{b)}\hfill \\ \text{5}\text{.4 }\times {\text{ 10}}^{\text{-8}}\hfill \\ \text{c)}\hfill \\ \text{6}\text{.3 }\times {\text{ 10}}^{\text{-}}{}^{\text{12}}\hfill \\ \begin{array}{l}\text{d)}\\ \text{2}\text{.7 }\times {\text{ 10}}^{\text{-8}}\end{array}\hfill \\ \begin{array}{l}\text{e)}\\ \text{2}\text{.7 }\times {\text{ 10}}^{-8}\end{array}\hfill \end{array}$