Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 17, Problem 17P
Interpretation Introduction

Interpretation:

Propanoic acid, 1-butanol and diethyl ether should be arranged according to the increasing boiling point.

Concept Introduction:

Carboxylic acid has maximum boiling point due to formation of dimer through intermolecular hydrogen bonding. Ether has low boiling point due to having weaker Vander Waal interaction. When positive end of dipole that is hydrogen linked with negative end of dipole (high electronegative atom such as oxygen, fluorine and nitrogen) results in hydrogen bonding.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…
Please draw, not just describe!
can you draw each step on a piece of a paper please this is very confusing to me

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Introduction to General, Organic and Biochemistry

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