The three isomers of benzenedicarboxylic acid are to be drawn. Concept introduction: Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

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Answer 1

Question

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مد

A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

Answer 2

Question

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

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Answer 3

Question

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

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Answer 4

Question

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

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Answer 5

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

Answer 6

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

Answer 7

Chapter 17, Problem 17.65SP

(a)

Interpretation Introduction

Interpretation:

The three isomers of benzenedicarboxylic acid are to be drawn.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Geometrical isomers are those isomers which show isomerism due to the presence of restricted rotation in a molecule.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The melting point of three isomers of benzenedicarboxylic acid is to be predicted.

Concept introduction:

Isomers are defined as molecules having the same molecular formula but different arrangement of atoms. Melting point of para isomers is generally higher than ortho and meta isomers.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17.1 - Prob. 17.1P Ch. 17.2 - Prob. 17.2P Ch. 17.3 - Prob. 17.3P Ch. 17.4 - Use resonance forms to show that the dipolar sigma...Ch. 17.6A - Prob. 17.5P Ch. 17.6A - Prob. 17.6P Ch. 17.6B - Propose a mechanism for the brommation of...Ch. 17.6B - Prob. 17.8P Ch. 17.6B - Prob. 17.9P Ch. 17.7 - Prob. 17.10P

Solution Summary: The author explains the melting point of three isomers of benzenedicarboxylic acid.

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