(a) Interpretation: The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn. Concept introduction: Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

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Answer 1

Question

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

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Answer 2

Question

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

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Answer 3

Question

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

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Answer 4

Question

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

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Answer 5

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Answer 6

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Answer 7

Chapter 17, Problem 17.23P

Interpretation Introduction

(a)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete detailed mechanism for the given 1, 2 and 1, 4 addition reaction is to be drawn.

Concept introduction:

Addition of the nucleophile at the carbonyl carbon atom called 1, 2 addition reaction or direct addition reaction and the addition of the nucleophile at the β carbon atom with respect to carbonyl carbon called 1, 4 addition reaction or conjugate addition reaction. The addition reaction occurs via the nucleophilic addition elementary step. The negative charge oxygen atom is protonated to form an uncharged alcohol product. In 1, 4 addition, the enol tautomerizes to aldehyde or ketone.

Answer 10

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Answer 12

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Answer 13

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

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Chapter 17 Solutions