
To determine:
a) The number of electrons transferred in the cell reaction.
b) The oxidation states of the
c) Draw the cell.

Answer to Problem 17.21QA
Solution:
a)
b)
Species | Transition metal | Oxidation state |
c)
Explanation of Solution
1) Concept:
In a voltaic cell, anode is the electrode at which oxidation takes place while cathode is the electrode at which reduction takes place. So, we can write two half-reactions based on the given cell reaction. The number of electrons transferred in the cell reaction can be determined by the number of electrons transferred in the half reactions.
The oxidation states of the transition metals can be determined by knowing the oxidation states of other elements in each species.
In a cell diagram, the anode and the species involved in the oxidation half reaction are written on the left and the cathode and the species involved in the reduction half reaction are written on the right. Single lines are used to separate the phases and a double line to represent the porous bridge separating the two compartments of the cell.
2) Given:
i) Cell reaction:
3) Calculations:
a)
Considering potassium as a spectator ion, the net ionic equation is written as
Separating the
Balancing the oxidation half reaction:
Balancing the reduction half reaction:
In each half reaction, there are 6 electrons transferred. So the total number of electrons transferred in the cell reaction is 6.
b)
In this cell reaction,
Let us assume “x” as oxidation state of
Let us assume that the oxidation state of
Oxidation state of
Let us assume that the oxidation state of
Thus, the oxidation states of the transition metals are
Species | Transition metal | Oxidation state |
c)
Cell diagram:
Applying the rules for writing the cell diagram, (anode on the left, cathode on the right, bridge in the middle), we get the following:
Conclusion:
From the given cell reaction, the two half reactions are written and the number of electrons transferred in cell reaction are determined. Applying the rules for assigning oxidation states, we got the oxidation states of transition metals. The cell is drawn using the balanced cell reaction and the rules for writing the cell diagram.
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Chapter 17 Solutions
Chemistry: An Atoms-Focused Approach
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