Chemistry: Atoms First V1
1st Edition
ISBN: 9781259383120
Author: Burdge
Publisher: McGraw Hill Custom
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Chapter 17, Problem 17.103QP
Barium is a toxic substance that can seriously impair heart function. For an X ray of the gastrointestinal tract, a patient drinks an aqueous suspension of 20 g BaSO4. If this substance were to equilibrate with the 5.0 L of the blood in the patient’s body, what would be [Ba2+]? For a good estimate, we may assume that the Ksp of BaSO4 at body temperature is the same as at 25°C. Why is Ba(NO3)2 not chosen for this procedure?
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
0.2 mol of KOH is added to
1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
0.10 mol of HI is added to
1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
other: ☐
0,0,...
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18
Ar
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
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Chapter 17 Solutions
Chemistry: Atoms First V1
Ch. 17.1 - Determine the pH at 25C of a solution prepared by...Ch. 17.1 - Determine the pH at 25C of a solution prepared by...Ch. 17.1 - Determine the pH at 25C of a solution prepared by...Ch. 17.1 - Prob. 1PPCCh. 17.1 - Prob. 17.1.1SRCh. 17.1 - Prob. 17.1.2SRCh. 17.2 - Starting with 1.00 L of a buffer that is 1.00 M in...Ch. 17.2 - Prob. 2PPACh. 17.2 - Prob. 2PPBCh. 17.2 - Prob. 2PPC
Ch. 17.2 - Prob. 17.3WECh. 17.2 - Prob. 3PPACh. 17.2 - Prob. 3PPBCh. 17.2 - Prob. 3PPCCh. 17.2 - Prob. 17.2.1SRCh. 17.2 - Prob. 17.2.2SRCh. 17.2 - Prob. 17.2.3SRCh. 17.2 - Prob. 17.2.4SRCh. 17.3 - Calculate the pH in the titration of 50.0 mL of...Ch. 17.3 - For the titration of 10.0 mL of 0.15 M acetic acid...Ch. 17.3 - Prob. 4PPBCh. 17.3 - Prob. 4PPCCh. 17.3 - Prob. 17.5WECh. 17.3 - Prob. 5PPACh. 17.3 - Prob. 5PPBCh. 17.3 - Which of the graphs [(i)(iv)] best represents the...Ch. 17.3 - Prob. 17.6WECh. 17.3 - Prob. 6PPACh. 17.3 - Prob. 6PPBCh. 17.3 - Prob. 6PPCCh. 17.3 - Prob. 17.3.1SRCh. 17.3 - Prob. 17.3.2SRCh. 17.3 - Prob. 17.3.3SRCh. 17.4 - Calculate the solubility of copper(II) hydroxide...Ch. 17.4 - Calculate the molar solubility and the solubility...Ch. 17.4 - Calculate the molar solubility and the solubility...Ch. 17.4 - Prob. 7PPCCh. 17.4 - Prob. 17.8WECh. 17.4 - Prob. 8PPACh. 17.4 - Prob. 8PPBCh. 17.4 - Prob. 8PPCCh. 17.4 - Prob. 17.9WECh. 17.4 - Predict whether a precipitate will form from each...Ch. 17.4 - Prob. 9PPBCh. 17.4 - Prob. 9PPCCh. 17.4 - Prob. 17.4.1SRCh. 17.4 - Prob. 17.4.2SRCh. 17.4 - Prob. 17.4.3SRCh. 17.5 - Prob. 17.10WECh. 17.5 - Calculate the molar solubility of AgI in (a) pure...Ch. 17.5 - Arrange the following salts in order of increasing...Ch. 17.5 - Prob. 17.11WECh. 17.5 - Determine if the following compounds are more...Ch. 17.5 - Prob. 11PPBCh. 17.5 - Prob. 11PPCCh. 17.5 - Prob. 17.12WECh. 17.5 - Prob. 12PPACh. 17.5 - Prob. 12PPBCh. 17.5 - Beginning with a saturated solution of AgCl, which...Ch. 17.5 - Prob. 17.5.1SRCh. 17.5 - Prob. 17.5.2SRCh. 17.6 - Prob. 17.13WECh. 17.6 - Prob. 13PPACh. 17.6 - Prob. 13PPBCh. 17.6 - Prob. 13PPCCh. 17.6 - Prob. 17.6.1SRCh. 17.6 - Prob. 17.6.2SRCh. 17 - Use Le Chteliers principle to explain how the...Ch. 17 - Describe the effect on pH (increase, decrease, or...Ch. 17 - Prob. 17.3QPCh. 17 - Prob. 17.4QPCh. 17 - Determine the pH of (a) a 0.40 M CH3COOH solution,...Ch. 17 - Determine the pH of (a) a 0.20 M NH3 solution, and...Ch. 17 - Which pair of substances can be dissolved together...Ch. 17 - Prob. 17.2VCCh. 17 - Prob. 17.3VCCh. 17 - Prob. 17.4VCCh. 17 - Prob. 17.7QPCh. 17 - Prob. 17.8QPCh. 17 - Calculate the pH of the buffer system made up of...Ch. 17 - Calculate the pH of the following two buffer...Ch. 17 - Prob. 17.11QPCh. 17 - Prob. 17.12QPCh. 17 - Prob. 17.13QPCh. 17 - The pH of blood plasma is 7.40. Assuming the...Ch. 17 - Calculate the pH of the 0.20 M NH3/0.20 M NH4Cl...Ch. 17 - Calculate the pH of 1.00 L of the buffer 1.00 M...Ch. 17 - Prob. 17.17QPCh. 17 - Prob. 17.18QPCh. 17 - Prob. 17.19QPCh. 17 - Prob. 17.20QPCh. 17 - The diagrams [(a)(d)] contain one or more of the...Ch. 17 - Prob. 17.22QPCh. 17 - Prob. 17.23QPCh. 17 - Prob. 17.24QPCh. 17 - Prob. 17.25QPCh. 17 - The amount of indicator used in an acid-base...Ch. 17 - Prob. 17.27QPCh. 17 - Prob. 17.28QPCh. 17 - Prob. 17.29QPCh. 17 - Prob. 17.30QPCh. 17 - Prob. 17.31QPCh. 17 - Prob. 17.32QPCh. 17 - Prob. 17.33QPCh. 17 - Prob. 17.34QPCh. 17 - A 25.0-,L solution of 0n100 M CH3COOH is titrated...Ch. 17 - A 10.0-mL solution of 0.300 M NH3 is titratee with...Ch. 17 - Prob. 17.37QPCh. 17 - Prob. 17.38QPCh. 17 - Prob. 17.39QPCh. 17 - Prob. 17.40QPCh. 17 - Diagrams (a) through (d) represent solutions at...Ch. 17 - Prob. 17.42QPCh. 17 - Prob. 17.43QPCh. 17 - Prob. 17.44QPCh. 17 - Write balanced equations and solubility product...Ch. 17 - Prob. 17.46QPCh. 17 - Prob. 17.47QPCh. 17 - Prob. 17.48QPCh. 17 - Prob. 17.49QPCh. 17 - Prob. 17.50QPCh. 17 - Prob. 17.51QPCh. 17 - The solubility of an ionic compound MX (molar mass...Ch. 17 - Prob. 17.53QPCh. 17 - Prob. 17.54QPCh. 17 - Prob. 17.55QPCh. 17 - Prob. 17.56QPCh. 17 - Prob. 17.57QPCh. 17 - A volume of 75 mL of 0.060 M NaF is mixed with 25...Ch. 17 - Prob. 17.59QPCh. 17 - Prob. 17.60QPCh. 17 - Prob. 17.5VCCh. 17 - Prob. 17.6VCCh. 17 - Prob. 17.7VCCh. 17 - How would the concentration of silver ion in the...Ch. 17 - Prob. 17.61QPCh. 17 - Prob. 17.62QPCh. 17 - Prob. 17.63QPCh. 17 - Prob. 17.64QPCh. 17 - The solubility product of PbBr2 is 8.9 106....Ch. 17 - Prob. 17.66QPCh. 17 - Calculate the molar solubility of BaSO4 in (a)...Ch. 17 - Prob. 17.68QPCh. 17 - Prob. 17.69QPCh. 17 - Prob. 17.70QPCh. 17 - Prob. 17.71QPCh. 17 - Prob. 17.72QPCh. 17 - Calculate the concentrations of Cd2+, Cd(CN)42 ,...Ch. 17 - Prob. 17.74QPCh. 17 - Prob. 17.75QPCh. 17 - (a) Calculate the molar solubility of...Ch. 17 - Prob. 17.77QPCh. 17 - Prob. 17.78QPCh. 17 - Prob. 17.79QPCh. 17 - Prob. 17.80QPCh. 17 - Prob. 17.81QPCh. 17 - Prob. 17.82QPCh. 17 - Prob. 17.83QPCh. 17 - Prob. 17.84QPCh. 17 - In a group 1 analysis, a student adds HCl acid to...Ch. 17 - Prob. 17.86QPCh. 17 - Prob. 17.87QPCh. 17 - Sketch the titration curve of a weak acid with a...Ch. 17 - Prob. 17.89QPCh. 17 - Prob. 17.90QPCh. 17 - Prob. 17.91QPCh. 17 - Tris [tris(hydroxymethyl)aminomethane] is a common...Ch. 17 - Prob. 17.93QPCh. 17 - Prob. 17.94QPCh. 17 - Prob. 17.95QPCh. 17 - Prob. 17.96QPCh. 17 - Prob. 17.97QPCh. 17 - Find the approximate pH range suitable for...Ch. 17 - Prob. 17.99QPCh. 17 - Prob. 17.100QPCh. 17 - Prob. 17.101QPCh. 17 - Prob. 17.102QPCh. 17 - Barium is a toxic substance that can seriously...Ch. 17 - The pKa of phenolphthalein is 9.10. Over what pH...Ch. 17 - Prob. 17.105QPCh. 17 - Prob. 17.106QPCh. 17 - Prob. 17.107QPCh. 17 - The molar mass of a certain metal carbonate, MCO3,...Ch. 17 - Prob. 17.109QPCh. 17 - Prob. 17.110QPCh. 17 - Describe how you would prepare a 1 -L 0.20 M...Ch. 17 - Phenolphthalein is the common indicator for the...Ch. 17 - Prob. 17.113QPCh. 17 - Prob. 17.114QPCh. 17 - Prob. 17.115QPCh. 17 - Prob. 17.116QPCh. 17 - Prob. 17.117QPCh. 17 - Prob. 17.118QPCh. 17 - When lemon juice is added to tea, the color...Ch. 17 - How many milliliters of 1.0 M NaOH must be added...Ch. 17 - Prob. 17.121QPCh. 17 - Prob. 17.122QPCh. 17 - Prob. 17.123QPCh. 17 - Prob. 17.124QPCh. 17 - Calcium oxalate is a major component of kidney...Ch. 17 - Water containing Ca2+ and Mg2+ ions is called hard...Ch. 17 - Prob. 17.127QPCh. 17 - Prob. 17.128QPCh. 17 - Prob. 17.129QPCh. 17 - (a) Referring to Figure 17.4, describe how you...Ch. 17 - Prob. 17.131QPCh. 17 - Prob. 17.132QPCh. 17 - Prob. 17.133QPCh. 17 - Prob. 17.134QPCh. 17 - Prob. 17.135QPCh. 17 - Prob. 17.136QPCh. 17 - A sample of 0.96 L of HCl gas at 372 mmHg and 22C...Ch. 17 - Prob. 17.138QPCh. 17 - The solutions (a) through (f) represent various...Ch. 17 - Prob. 17.140QPCh. 17 - Prob. 17.141QPCh. 17 - Which of the acids in Table 16.5 (page 732) can be...Ch. 17 - Prob. 17.2KSPCh. 17 - Prob. 17.3KSPCh. 17 - How much sodium fluoride must be dissolved in 250...
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