(a) Interpretation: The net ionic equation needs to be determined and balanced in the acidic medium. Concept introduction: The rules to balance redox reactions in basic medium are as follows: Determine the oxidation numbers of the elements and write the oxidation and reduction half equation. Balance the atoms of elements other than H and O atoms. Use H 2 O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Question

Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

Answer 1

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Protecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑

Draw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He command

Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9

Answer 2

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Answer 3

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Answer 4

Question

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

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Answer 5

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 6

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 7

Chapter 17, Problem 10QAP

Interpretation Introduction

(a)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The net ionic equation needs to be determined and balanced in the acidic medium.

Concept introduction:

The rules to balance redox reactions in basic medium are as follows:

Determine the oxidation numbers of the elements and write the oxidation and reduction half equation.

Balance the atoms of elements other than H and O atoms. Use H₂ O to balance the number of O atoms, H+ to balance the number of H atoms and the electrons for charge balance. Equalize the number of electrons on both the half reactions and then add the half reactions.

Answer 12

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Answer 23

Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Prob. 3QAP Ch. 17 - Balance the following reactions in acid: (a)...Ch. 17 - Write balanced equations for the following...Ch. 17 - Write balanced equations for the following...Ch. 17 - Prob. 7QAP Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Prob. 10QAP

Solution Summary: The author explains how the net ionic equation must be determined and balanced in the acidic medium.

Chapter 17 Solutions