(a) Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified. Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Question

PQ-10. What is the major product of this reaction? (A) (C) 930 Me HO O=S=O O-8-CF, C 어 Me H+ OH 270 O 0-5-0 O=S=O O-S-CF CF3 2

Answer 1

Question

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

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PQ-10. What is the major product of this reaction? (A) (C) 930 Me HO O=S=O O-8-CF, C 어 Me H+ OH 270 O 0-5-0 O=S=O O-S-CF CF3 2

Predict the major organic product(s) of the following reactions. Include stereochemistry when necessary. Write NR if no reaction, try to explain.

Q2: Explain why epoxides that react in an SN1 manner will not show any stereochemical inversion in the product. Q3: Rationalize why Alcohol B will react under the indicated reaction conditions, but Alcohol A will not. A ☑ OH B OH PBr3 R-Br

Answer 2

Question

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

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Answer 3

Question

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

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Answer 4

Question

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

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Answer 5

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 6

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 7

Chapter 16.6, Problem 14P

Interpretation Introduction

(a)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 8

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 9

Interpretation Introduction

(b)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 10

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 11

Interpretation Introduction

(c)

Interpretation: Whether the given substituent exhibits an electron-withdrawing or an electron-donating inductive effect is to be identified.

Concept introduction: The atoms which are more electronegative than carbon pull charge density away from carbon and exhibit an electron-withdrawing inductive effect. Alkyl groups donate electron density, thus exhibit an electron donation inductive effect.

Answer 12

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Answer 23

Ch. 16.1 - Prob. 1P Ch. 16.2 - Prob. 2P Ch. 16.3 - Prob. 3P Ch. 16.4 - Prob. 4P Ch. 16.5 - Prob. 5P Ch. 16.5 - Prob. 6P Ch. 16.5 - Prob. 9P Ch. 16.5 - Problem 18.9 Draw the product of each reaction a....Ch. 16.5 - Prob. 11P Ch. 16.5 - Prob. 12P

Solution Summary: The author analyzes whether a given substituent exhibits an electron-withdrawing or donating inductive effect. The atoms which are more electronegative than carbon pull charge density away from carbon.

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Chapter 16 Solutions