(a) Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn. Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl 3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

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Answer 1

Question

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

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Answer 2

Question

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

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Answer 3

Question

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

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Answer 4

Question

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

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Answer 5

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Answer 6

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Answer 7

Chapter 16.5, Problem 13P

Interpretation Introduction

(a)

Interpretation: The resonance structures for the carbocation formed after loss of a leaving group from phytyldiphosphate is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Answer 8

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Answer 9

Interpretation Introduction

(b)

Interpretation: The two-step mechanism for Friedel–Crafts alkylation of 1, 4-dihydroxynaphthoic acid with carbocation to form X is to be drawn.

Concept introduction: The Friedel-Craft alkylation is a type of electrophilic substitution reaction. AlCl3 is used as Lewis acid which reacts with the alkyl chloride to a form a Lewis acid-base complex.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 16.1 - Prob. 1P Ch. 16.2 - Prob. 2P Ch. 16.3 - Prob. 3P Ch. 16.4 - Prob. 4P Ch. 16.5 - Prob. 5P Ch. 16.5 - Prob. 6P Ch. 16.5 - Prob. 9P Ch. 16.5 - Problem 18.9 Draw the product of each reaction a....Ch. 16.5 - Prob. 11P Ch. 16.5 - Prob. 12P

Solution Summary: The author explains that the two-step mechanism for Friedel-Crafts alkylation is a type of electrophilic substitution reaction.

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Chapter 16 Solutions